Vinylogous Esterの接触還元(第1報)
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概要
- 論文の詳細を見る
3-Alkoxy-5,5-dimethyl-2-cyclohexenones were reduced to trans-3-alkoxy-5,5-dimethyl-cyclohexanols over Raney-nickel in ethanol in over 90% yield. In the case of 2-methyl-3-ethoxy-5,5-dimethyl-2-cyclohexenone and 2-butyl-3-methoxy-2-cyclopentenone, a large amount of the starting materials was recovered. On the other hand, two methyl vinylogous esters of 2-methyl-4-hydroxy-1,3-cyclopentanedione were reduced to the corresponding tetrahydro compounds and demethoxy perhydro compounds.
- 公益社団法人日本薬学会の論文
- 1970-09-25
著者
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的場 勝英
Faculty Of Pharmaceutical Sciences Toyama Medical & Pharmaceutical University
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山崎 高応
富山医科薬科大学 薬
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山崎 高応
富山大学薬学部
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的場 勝英
富山大学薬学部
関連論文
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- Reduction of Vinylogous Thioesters with Lithium Aluminum Hydride. I. Reduction of β-Phenylthio-α, β-unsaturated Cyclic Ketones
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- Reduction of O-Alkylated Imides
- Synthesis in the Diazasteroid Group. XVIII. Syntheses of the 9,17-Diazasteroid System
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