水素化リチウムアルミニウムによるVinylogous Esterの還元(第4報)

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概要

• 論文の詳細を見る

• 3-Methoxy-4-hydroxy-5-methyl-2-cyclopentenone (VI), a good model for five-membered vinylogous ester of acutumine (I), was reduced with lithium aluminum hydride, to 4-methyl-5-hydroxy-2-cyclopentenone (X), 2-methyl-4-cyclopentene-1,3-diol (XI_<(VI)>) and 2-methyl-cyclopentane-1,3-diol (XII_<(VI)>). 3-Methoxy-4-methyl-5-hydroxy-2-cyclopentenone (VII) was reduced to 4-hydroxy-5-methyl-2-cyclopentenone (XIII). The revised mechanism was proposed and the errors in the previous papers based on ambiguous experimental data were corrected.

• 公益社団法人日本薬学会の論文
• 1972-03-25

著者

• 的場 勝英

  Faculty Of Pharmaceutical Sciences Toyama Medical & Pharmaceutical University

• 山崎 高応

  富山医科薬科大学 薬

• 山崎 高応

  富山大学薬学部

• 的場 勝英

  富山大学薬学部

関連論文

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