水素化リチウムアルミニウムによるVinylogous Esterの還元(第6報)

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概要

• 論文の詳細を見る

• 2-Methyl-3-methoxy-4-t-butyl-2-cyc1opentenone (VI) and 3-methoxy-4-t-butyl-2-cyclohexenone (IX) were reduced to the corresponding β-methoxy-allyl alcohols with excess lithium aluminum hydride. Under the same conditions, 2-methyl-3-methoxy-5-t-butyl-2-cyclopentenone (VII) was reduced to saturated ketones, allyl alcohols, and diols. On the other hand, from 3-methoxy-6-t-butyl-2-cyclohexenone (X), β-methoxyallyl alcohols, saturated ketones, allyl alcohols, and diols were obtained. The substituent effect of t-butyl group in five-membered and six-membered vinylogous esters was discussed, and a mechanism for the formation of diols was proposed.

• 公益社団法人日本薬学会の論文
• 1973-11-25

著者

• 的場 勝英

  Faculty Of Pharmaceutical Sciences Toyama Medical & Pharmaceutical University

• 山崎 高応

  富山医科薬科大学 薬

• 山崎 高応

  富山大学薬学部

• 的場 勝英

  富山大学薬学部

関連論文

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