Reaction of Vinylogous Esters with Grignard Reagent

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概要

• 論文の詳細を見る

• With Grignard reagent, five-membered vinylogous esters gave 1,2-addition products in a similar fashion to the cases for six-membered vinylogous esters. On the other hand, the six-membered vinylogous ester substituted with t-butyl group at the α-position of carbonyl function also gave only 1,2-addition product. However the five-membered vinylogous ester substituted with hydroxy group at the α-position of methoxy group gave 1,2-addition product and 1,4-addition products. In these Grignard reactions, the catalytic effect of cuprous chloride was scarcely observed.

• 公益社団法人日本薬学会の論文
• 1976-01-25

著者

• 前田 隆志

  Faculty Of Pharmaceutical Sciences University Of Toyama

• 的場 勝英

  Faculty Of Pharmaceutical Sciences Toyama Medical & Pharmaceutical University

• 的場 勝英

  Faculty Of Pharmaceutical Sciences Osaka University

• 山崎 高応

  富山医科薬科大学 薬

• 山崎 高応

  Faculty of Pharmaceutical Sciences

• 長瀬 恵子

  Faculty of Pharmaceutical Sciences, University of Toyama

• 長瀬 恵子

  Faculty Of Pharmaceutical Sciences University Of Toyama

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