Studies on the Metal Chelate Compounds of Phenazine Derivatives. XII. Far-infrared Spectra of the Metal Chelates of Hydroxyphenazine Derivatives
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概要
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The far-infrared spectra of metal chelates of oxine-like ligands, 2,3-dimethyl-5-hydroxyquinoxaline, 1-hydroxyphenazine, 6-hydroxybenzo [a] phenazine, 8-hydroxybenzo [a] phenazine and 11-hydroxybenzo [a] phenazine, with divalent metal ions (Co^<2+>, Ni^<2+>, Cu^<2+>, and Zn^<2+>) are investigated. The metal-oxygen stretching bands have been assigned tentatively to the 294-219cm^<-1>. Structure of these metal chelates have been proposed from the magnetic moments, the number of metal-oxygen stretching bands and the spectral pattern in the 600-400 cm^<-1> region. The structure of copper chelates, except for 11-hydroxybenzo [a] phenazine copper chelate, is trans square planar. The relationship between the M-O stretching band and atomic number of central metal has been discussed.
- 公益社団法人日本薬学会の論文
- 1976-05-25
著者
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喜谷 喜徳
Faculty of Pharmaceutical Sciences Nagoya City University
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稲垣 健治
Faculty of Pharmaceutical Sciences Nagoya City University
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