Magnetic Circular Dichroic Spectra of Various Adducts of Co (II)-Bovine Carbonic Anhydrase
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概要
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On the basis of magnetic circular dichroic (MCD) spectra, the coordination geometries of various adducts of cobalt (II)-bovine carbonic anhydrase were determined. The 8-quinolinecar-boxylate, acetate and oxalate adducts of cobalt (II)-bovine carbonic anhydrase, which had two clearly separated negative MCD bands at 17500 cm^<-1> and 21000-22000 cm^<-1>, were five-coordinate. The MCD spectra of the Cl^-, Br^-, benzoate, and 3-quinolinecarboxylate adducts of cobalt (II)-bovine carbonic anhydrase were very complex and were interpreted in terms of the overlapping of MCD spectra of tetrahedral and five-coordinate adducts. The coordination geometry of the alkaline form of cobalt (II)-bovine carbonic anhydrase is discussed on the basis of the above results.
- 公益社団法人日本薬学会の論文
- 1984-07-25
著者
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喜谷 喜徳
Faculty of Pharmaceutical Sciences Nagoya City University
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野路 雅英
Faculty of Pharmaceutical Sciences, Nagoya City University
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廣瀬 順造
Department Of Food Science And Technology Faculty Of Engineering Fukuyama University
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廣瀬 順造
Faculty of Engineering, Department of Food Science and Technology, Fukuyama University
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喜谷 喜徳
名古屋市立大学薬学部
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野路 雅英
Faculty Of Pharmaceutical Sciences Nagoya City University
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野路 雅英
名古屋市大 薬
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