Synthesis of 1-(Methylthio) phenazine Platinum (II) and Its S-demethylated Complexes
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概要
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1-(Methylthio) phenazine (mtph) reacts with platinum (II) and palladium (II) in acetone-water to give orange complexes. The mtph coordinates to metal through the sulfur and nitrogen atoms as a bidentate ligand, and the two halogen atoms of the complexes are in cis-configuration. When the orange complex, PtCl_2 (mtph), was refluxed in N, N-dimethylformamide, a reddish violet S-demethylated complex was produced. On the other hand, PdCl_2 (mtph) did not give any demethylated complexes under similar conditions.
- 公益社団法人日本薬学会の論文
- 1978-06-25
著者
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喜谷 喜徳
Faculty of Pharmaceutical Sciences Nagoya City University
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稲垣 健治
Faculty of Pharmaceutical Sciences Nagoya City University
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