RING OPENING OF CYCLOPROPANECARBOXYLATES USING SAMURIUM(II) DIIODIDE (SmI_2)-HMPA-THF SYSTEM

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概要

• 論文の詳細を見る

• Cyclopropane ring of 2- and 2,3-substituted cyclopropanecarboxylates (1) was regioselectively cleaved using SmI_2-HMPA-THF system in the presence of tert-BuOH to give 4- and 3,4-substituted butyrates (2) in moderate to good yields.

• 公益社団法人日本薬学会の論文
• 1995-04-15

著者

• 太田 俊作

  Kyoto Pharmaceutical University

• 山下 正行

  Kyoto Pharmaceutical University

• 川崎 郁勇

  Kyoto Pharmaceutical University

• 奥山 和典

  Kyoto Pharmaceutical University

• 大原 隆

  Kyoto Pharmaceutical University

• 川崎 郁勇

  京都薬大

• 太田 俊作

  京都薬科大学薬学部

• 太田 俊作

  Kyoto College Of Pharmacy

• 山下 正行

  京都薬科大学薬学部

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