Singlet and Triplet Excited State Photochemistry of Tricyclo-[5. 2. 2. 0^<2,6>] undeca-3,10-dien-9-one Derivatives
スポンサーリンク
概要
- 論文の詳細を見る
The photochemical behavior of tricyclo [5. 2. 2. 0^<2,6>] undeca-3,10-dien-9-one ring system (4), which was prepared by Diels-Alder reaction of cyclohexadienone derivatives and cyclopentadiene, has been studied under triplet sensitization and direct irradiation. In the triplet state, this ring system undergoes the oxa-di-π-methane (ODPM) rearrangement, while the 1,3-acyl migration occurs from the singlet state. The triplet energy was estimated to be between 70 and 72 kcal/mol on the basis of sensitization by various sensitizers.
- 公益社団法人日本薬学会の論文
- 1977-12-25
著者
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米光 宰
Faculty of Pharmaceutical Sciences, Hokkaido University
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米光 宰
Faculty Of Pharmaceutical Sciences Hokkaido University
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平尾 健一
Faculty of Pharmaceutical Sciences, Hokkaido University
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海野 重視
Faculty of Pharmaceutical Sciences, Hokkaido University
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三浦 偉俊
Faculty of Pharmaceutical Sciences, Hokkaido University
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三浦 偉俊
Faculty Of Pharmaceutical Sciences Chiba University
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平尾 健一
Faculty Of Pharmaceutical Sciences Hokkaido University
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海野 重視
Faculty Of Pharmaceutical Sciences Hokkaido University
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