Synthesis of (-)-Muricatacin
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概要
- 論文の詳細を見る
The synthesis of (-)-muricatacin starting from 1-bromododecane and 2-pentyn-1-ol is described. 2-Pentadecyn-1-ol (4), which was prepared from 1-bromododecane (2) and 2-pentyn-1-ol (3), was converted to epoxy alcohol 6 through a two-step reaction sequence, 6 being successively submitted to tosylation, iodination, chain extension with tert-butyl lithioacetate, and acid-catalyzed cyclization to give (-)-muricatacin (1a). Recrystallization afforded optically pure 1a.
- 社団法人日本農芸化学会の論文
- 1993-06-23
著者
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Araki T
Faculty Of Bioresources Mie University
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Arai Takamitsu
Faculty Of Bioresources And Center For Molecular Biology And Genetics Mie University
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Tanaka Akira
Department of Health and Nutrition, College of Human and Environmental Studies, Kanto-Gakuin Univers
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Tanaka A
Faculty Of Bioresources Mie University
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MAKABE Hidefumi
Department of Applied Biological Chemistry, Faculty of Agriculture
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ORITANI Takayuki
Department of Applied Biological Chemistry, Faculty of Agriculture
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Makabe H
Shinshu Univ. Nagano Jpn
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Makabe Hidefumi
Department Of Applied Biological Chemistry Faculty Of Agriculture
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Oritani Takayuki
Department Of Agricultural Chemistry Faculty Of Agriculture Tohoku University
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Tanaka Akira
Department Of Diagnostic Pathology Jichi Medical University
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TANAKA Akira
Department of Agricultural Chemistry, Faculty of Agriculture, Tohoku University
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