Photochromism and Luminescence Properties of a 2-(2,4-Dinitrobenzyl) Pyridine Dispersed in Polymer Films
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概要
- 論文の詳細を見る
Both absorption atud Itrminescerace spectra of' a 2-(2,4-dinitrobenzyl)pyridit'ue dispersed in polytaner filnas xvere tneastrred in steady state at loxv teuauperattrre in order to elucidate flue electronicstates as well as tlue plxotochrotaaic rearctiota ;tccotaaparuied witla a proton transfer. Three absorp-tiora barads due to the plaotoprodtrct were o1.cser'ved ira a visible regior'n after' tlae UV plaotolysis..Jtrdgirag f'rona tlte tlterraa?tl belaavior of' tlaese bands, tlae photoprodtrct cotasists of' two diflerer'xtkinds of' species (NH atad OH f'ornas), and tlae OH forum t1tertaaall.3' changes to tlae NH fornaa. XVealso fotrnd that botla tlae INH atad OH fornus optic?t11)' retttrn back to tlae colorless forrn (CH2 f'orraa)Qll tlae plaotolysis of' visible liglxt. Tlae ltruuaiuaescence spectr?r dtre to the NH auad OH fortaas xvereobserx'ed for tlae first time. Tlae ltrtaairaescence ['rotaa tlae OH ['orna l'xas vibronic strtucttrres. xvhiletlaat f'ronn tlae NH fortaa is broad xvitl?otrt aray x'ibrorxic strtrctttres. Tlue slaorter decay tiuaae of' t1'?eluraairaescerace in conaparisoru xvitlt tlae estirtasxted r'adiative lifetiraae suggests th;tt tire nort-radiativerelaxation process is responsible fox' tlae deca)z.
- 社団法人日本物理学会の論文
- 1999-05-15
著者
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TAKEDA Jun
Department of Physics,Faculty of Science,Nagoya University
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Shinohara Shunjiro
Department Of Physics Faculty Of Sciences University Of Tokyo
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Shinohara Shunjiro
Department Of Physics Faculty Of Science The University Of Tokyo
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Takeda J
Nagoya Univ. Nagoya
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Takeda Jun
Department Of Physics Division Of Material Science Nagoya University:crest Japan Science And Technol
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Takeda Jun
Department Of Physics Faculty Of Science Nagoya University
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SHINOHARA Saiji
Department of Physics,Faculty of Engineering,Yokohama National University
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OOIKE Tomoyuki
Department of Physics,Faculty of Engineering,Yokohama National University
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KURITA Susumu
Department of Physics,Faculty of Engineering,Yokohama National University
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Takeda Jun
Department Of Diabetes And Endocrinology Division Of Molecule And Structure Gifu University School O
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Kurita S
Faculty Of Engineering Yokohama National University
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Kurita Susumu
Department Of Materials Engineering Yokohama National University
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Ooike Tomoyuki
Department Of Physics Faculty Of Engineering Yokohama National University
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Shinohara S
Department Of Physics Faculty Of Engineering Yokohama National University
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Kurita Susumu
Institute Of Physics The University Of Tsukuba:hiroshima Branch Japan Meteorological Agency
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Takeda Jun
Department Of Cell Biology Institute For Molecular And Cellular Regulation Gunma University
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Takeda Jun
Department Of Biological Sciences Graduate School Of Science Tokyo Metropolitan University
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KURITA Susumu
Faculty of Engineering, Yokohama National University : National Magnet Laboratory, Massachusetts Institute of Technology
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