Magnetic Resonance Studies of the Quasi-One-Dimensional Conductor α'-Na_xV_2O_5
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概要
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We present the EPR and NMR results on the quasi-one-dimensional conductor .z-Na.V.0, (x= l .0, 0.9 and 0.78) in the temperature range from 12 K to 397 K. The spinsusceptibility extracted from EPR measurements has a broad maximum around roomtemperature. The "V NMR line shift associated with the V" Jon increases withdecreasing temperature below room temperature. l'he ground state of the V" ion isspin-singlet and it is understood as bipolaronic state, which is the electron pairs of theadjacent V" ions formed by the strong electron-phonon interaction. In the case ofx= 1.0, it is pointed out that there are the vanadium zigzag chains occupied by theonly V" ions, where the electron wave function overlaps directly.
- 社団法人日本物理学会の論文
- 1986-07-15
著者
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NAGASAWA Hiroshi
Institute of Physics,University of Tsukuba
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Ogawa K
Tokyo Inst. Technol. Tokyo
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Ogawa Keiko
Institute Of Physics University Of Tsukuba
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Onoda Masashige
Institute For Molecular Science Okazaki National Research Institutes
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Onoda Masashige
Institute Of Physics University Of Tsukuba:institute For Molecular Science Okazaki National Research
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Nagasawa Hiroshi
Institute For Solid State Physics The University Of Tokyo
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