X-Ray Study of the Room Temperature Structure in Monoclinic TIS

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概要

• 論文の詳細を見る

• TIS is known as a mixed valence compound containing monovalent and trivalent thallium ions. The structure of the newly found monoclinic TIS has been analyzed using three-dimensional single crystal diffraction data. Space group C2 : a= 11.018(6), b= 11.039(15), c= 60.16(7)Å, β= 100.69°(4) and Z= 128. The structure is characterized by layers formed of corner-connected TI^<+3>S_4 tetrahedra. Monovalent TI^<1+> ions are located between the layers and have trigonal prismatic coordination of the sulfur ions. The structure is a variation of the TIGaSe_2 type with fourfold modulation along the c-axis. The modulation is caused by cooperative distortion of trigonal prisms around the monovalent TI^<1+> ions.

• 社団法人日本物理学会の論文
• 1993-09-15

著者

• NAKAMURA Kazuo

  Department of Management and Information Systems Science Nagaoka University of Technology

• KASHIDA Shoji

  Faculty of Science,Niigata University

• Kashida S

  Niigata Univ. Niigata

• Kashida Shoji

  Department Of Environmental Science Niigata University

• Nakamura Kazuo

  Department Of Clinical Pharmacy And Pharmacology Graduate School Of Medical And Dental Sciences Kago

• Nakamura Kazuo

  Department Of Biological Sciences University Of Lethbridge

• Nakamura Kazuo

  Department Of Physics Niigata University

• Nakamura Kazuo

  Department Of Biochemistry Kitasato University School Of Medicine

• Nakamura Kazuo

  Department of Applied Chemistry and Biotechnology, Faculty of Engineering, Yamanashi University

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