One-Dimensional Stacking Disorder in a Linear Chain Compound (CH_3)_3NHCdCl_3
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概要
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The structural phase transition of a linear chain compound (CH.).NHCdCl.(TrMCC) was studied by X-ray diffraction method. Accompanying the phasetransition from the (I x v'?) structure to the (2 x (3) structure, strong diffusestreaks were observed along the b" direction. In order to explain the observedpeak profiles, a simplified model was presented. In this model, the layers madeof rather tightly coupled CdCl3 chains were assurned to stack with probabilities.The diffraction intensity was analyzed using the matrix method given by Kakinokiand Komura. The calculation which incorporates tlae effect of the phase shift due tothe displacements normal to the stacking direction was found to reproduce theexperimental results fairly well. The streaks observed in the (3 x 2) phase werealso discussed.
- 社団法人日本物理学会の論文
- 1985-10-15
著者
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Kashida Shoji
Department Of Environmental Science Niigata University
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Fukumoto Toshiro
Department Of Physics Faculty Of Science Niigata University:the Fukukawa Electric Co. Ltd
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Fukumoto Toshiro
Department of Electrical and Electronic Engineering, Faculty of Engineering, Kobe University
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