Theoretical Analysis of the Mossbauer Data in Some Fe^<2+> Compounds
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概要
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The electronic ground state wave functions in FeCO_3 and FeTiO_3 are deduced from the nuclear quadrupole coupling data. With these wave functions, the contribution of the intra atomic magnetic dipolar interaction and that of the electron orbital current effect to the internal magnetic field are calculated. A similar analysis is done also on FeF_2. The magnitude of the Fermi interaction, which is obtained by subtracting the above mentioned contributions from the observed value of the internal magnetic field, shows a reasonable dependence on the electronegativity of negative ion. Also the energy separations of the crystalline field levels in FeF_2 are calculated by use of the Mossbauer data and the data of the paramagnetic resonance experiment on Fe^<2+> in ZnF_2.
- 社団法人日本物理学会の論文
- 1964-06-05
著者
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Okiji Ayao
Department Of Aplied Physics Faculty Of Engineering Osaka University
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Okiji Ayao
Department Of Physics Osaka University:(present) The Institute For Solid State Physics The Universit
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KANAM0RI Junjiro
Department of Physics, Osaka University
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Kanam0ri Junjiro
Department Of Physics Osaka University
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