気相試料導入-電気加熱原子吸光分析による鉄鋼中の銀の定量(分析・解析)

概要

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A trace amount of silver was determined by an electrically heated quartz tube atomization (QTA) atomic absorption spectrometry (AAS) with continuous-flow gas-phase sample introduction technique by use of both tartaric and hydrochloric acids as reaction media, and potassium tetrahydroborate (III) as a reductant. Under the optimized experimental conditions, the best attainable detection limit for silver at 328.07nm was 0.4ngmL^<-1>. The instrumental precision expressed as the relative standard deviation (RSD) from ten replicate measurements of 50ngmL^<-1> for silver by QTA-AAS was 4.0%. After the effects of diverse elements on the determination of silver were examined, this method was applied to the determination of low concentrations of silver in steels. The results obtained by the present method were in good agreement with the certified values.
社団法人日本鉄鋼協会の論文
2005-05-01