気相試料導入-誘導結合プラズマ発光分光分析による鉄鋼中の銅の定量

概要

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Copper in steels was determined by inductively coupled plasma atomic emission spectrometry with gas-phase sample introduction in a reaction medium of citric acid. The gaseous copper species, as yet unidentified, was phase-separated in a gas-liquid separator and directed via a stream of argon carrier gas to an inductively coupled plasma for atomic emission spectrometry. Under the optimized experimental conditions, the best attainable detection limit at CuI 324.754 nm line was 1.5 ng/ml with a linear dynamic range of 10 to 500 ng/ml in concentrations. The presence of several diverse elements was found to cause more or less a depressing interference by the proposed technique. When copper in steels was determined, a large amount of iron in the solution caused a severe depressing interference. Of the extraction solvents examined, diethyl ether was found to be the most preferable to separate iron from copper in the sample solution. The proposed method was applied to the determination of low concentrations of copper in steels. The results obtained by this method were in good agreement with the certified values.
社団法人日本鉄鋼協会の論文