Determination of Association Constant of Inclusion Complex between Cyclophane and Biological Relevant Phosphates by Fast Atom Bombardment Mass Spectrometry
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概要
- 論文の詳細を見る
By 1H NMR spectrometry it is impossible to confirm the association constant (Ks) of the host-guest complex which peaks of guest become broad and overlapped by host peaks. In order to solve the obstacles and raise the usefulness of FAB mass spectrometry in host-guest chemistry, we examined whether FAB mass spectrometry would be a suitable measurement tool for Ks value of the host-guest complex. As the result, the Ks value calculated by FAB mass spectrometry was mostly in agreement with the Ks value calculated by 1H NMR spectrometry. It was concluded that FAB mass spectrometry is available for the determination of Ks value.
- 日本質量分析学会の論文
- 2003-12-01
著者
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Motani Kou
日本大学 薬学部臨床医学ユニット
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Kimura Yumiko
College Of Pharmacy Nihon University
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METORI Koichi
College of Pharmacy, Nihon University
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MIYAKE Muneharu
College of Pharmacy, Nihon University
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Metori Koichi
Chemical Analytical Center College Of Pharmacy Nihon University
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Metori Koichi
College Of Pharmacy Nihon University
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Metori Koichi
Coll. Of Pharmacy Nihon Univ.
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Miyake Muneharu
College Of Pharmacy Nihon University
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Miyake Muneharu
School Of Pharmacy Nihon Univ.
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