Interactive Force between Cyclodextrin Inclusion Complexes Studied by Atomic Force Microscopy
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概要
- 論文の詳細を見る
Change in the intermolecular interaction between cyclodextrins (CyDs) with guest materials was observed by measuring the adhesion force using atomic force microscopy (AFM) in air. The observed adhesion force with water as the guest material is weaker for $\alpha$-CyD (composed of 6 glucose) than $\beta$-CyD (7 glucose), contrary to the fact that $\alpha$-CyD is more hydrophilic than $\beta$-CyD, indicating that the intrinsic interaction of molecules could be obtained separately from the meniscus force even in air. In addition, the adhesion force depends on the type of guest molecules (H2O, para-nitrophenol, and triethylendiamine) for $\alpha$-CyDs, but not for $\beta$-CyDs. The observed change was explained well by the change in the dipole moment induced by the structural deformation due to the guest materials.
- Publication Office, Japanese Journal of Applied Physics, Faculty of Science, University of Tokyoの論文
- 2001-06-30
著者
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Yasuda Satoshi
Institute Of Advanced Energy Kyoto University
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Yamashita Mikio
Department Of Applied Physics Hokkaido University
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Komiyama Makoto
Research Center For Advanced Science And Technology The University Of Tokyo
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Takeuchi Osamu
Institute Of Applied Physics And 21st Coe University Of Tsukuba
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Futaba Don
Institute Of Applied Physics Crest Japan Science And Technology Corporation (jst) University Of Tsuk
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Sumaoka Jun
Research Center For Advanced Science And Technology The University Of Tokyo
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Shigekawa Hidemi
Institute Of Applied Physics And 21st Coe University Of Tsukuba
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Morita Ryuji
Department Of Applied Physics Faculty Of Engineering University Of Tokyo
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Oyama Shigeo
Institute Of Applied Physics Crest Japan Science And Technology Corporation 'jst) University Of
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Miyake Koji
Institute Of Applied Physics And Crest Japan Science And Technology Corporation (jst) University Of
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Futaba Don
Institute of Applied Physics, CREST, Japan Science and Technology Corporation (JST), University of Tsukuba, Tsukuba 305-8573, Japan
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Komiyama Makoto
Research Center for Advanced Science and Technology, University of Tokyo, Komaba, Tokyo 153-8904, Japan
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Sumaoka Jun
Research Center for Advanced Science and Technology, University of Tokyo, Komaba, Tokyo 153-8904, Japan
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Oyama Shigeo
Institute of Applied Physics, CREST, Japan Science and Technology Corporation (JST), University of Tsukuba, Tsukuba 305-8573, Japan
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Yasuda Satoshi
Institute of Applied Physics, CREST, Japan Science and Technology Corporation (JST), University of Tsukuba, Tsukuba 305-8573, Japan
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Miyake Koji
Institute of Applied Physics, CREST, Japan Science and Technology Corporation (JST), University of Tsukuba, Tsukuba 305-8573, Japan
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