Synthesis of .BETA.-ZrClN by thermal decomposition of zirconium(IV) amide trichloride.
スポンサーリンク
概要
- 論文の詳細を見る
The zirconium amide trichloride ZrCl<SUB>3</SUB>(NH<SUB>2</SUB>)·7NH<SUB>3</SUB> was prepared by the reaction of ZrCl<SUB>4</SUB> with liquid ammonia. On heating up to 600°C in flowing ammonia gas, the amide was efficiently converted into β-ZrClN, whereas under vacuum it was decomposed to a different product. The decomposition processes were followed by using a quartz spring balance.
- 公益社団法人 日本化学会の論文
著者
-
Yamanaka Shoji
Department Of Applied Chemistry Faculty Of Engineering Hiroshima University
-
Hattori Makoto
Department Of Agricultural Chemistry The University Of Tokyo
-
Ohashi Masao
Department of Applied Chemistry, Faculty of Engineering, Hiroshima University
関連論文
- Adenosquamous carcinoma of the pancreas associated with humoral hypercalcemia of malignancy (HHM)
- Intravascular Lymphoma: Usefulness of Liver Biopsy in the Clinical Setting
- Soluble Egg Shell Membrane Protein as a Regulating Material for Collagen Matrix Reconstruction
- Aminopropyl-Glucose Sequentially Grafted Mesoporous Silica Nanocomposite as a Novel Boron Adsorbent
- Protective Oxidation of a Layer Structured Manganese Titanate, Rb_xMn_xTi_O_4 (x=0.75) in Acidic Solutions
- Antigenicity of Modified β-Lactoglobulin Examined by Three Different Assays
- Grade I Lymphomatoid Granulomatosis with Increased Uptake of [^F] Fluorodeoxyglucose in Positron Emission Tomography : A Case Report
- Successful Treatment of Adrenocortical Carcinoma with Pulmonary Metastasis in a Child : Report of a Case
- Epitaxial Growth of Ba_2YCu_3O_x Thin Film on Epitaxial ZrO_2/Si(100) : Electrical Properties of Condensed Matter
- Characterization of Layered Polysilane
- ^Xe NUCLEAR MAGNETIC RESONANCE STUDY ON THE PORE STRUCTURES OF SiO_2-TiO_2 SOL PILLARED CLAYS
- Hexosaminidase-altered Aberrant Crypts, Carrying Decreased Hexosaminidase α and β Subunit mRNAS, in Colon of 1,2-Dimethylhydrazine-treated Rats
- Improved Physical and Biochemical Features of a Collagen Membrane by Conjugating with Soluble Egg Shell Membrane Protein
- Contribution of the Net Charge to the Regulatory Effects of Amino Acids and ε-Poly(L-lysine) on the Gelatinization Behavior of Potato Starch Granules
- Interfacial Behavior of Fatty-Acylated Sericin Prepared by Lipase-Catalyzed Solid-Phase Synthesis
- Thermal Behavior of Fowl Feather Keratin
- Effect of Swelling on the Superconducting Characteristics in Electron-Doped β-ZrNCl and HfNCl
- Conversion of Brain-Specific Complex Type Sugar Chains by N-Acetyl-β-_D-Hexosaminidase B
- Aberrant CD20 Expression in Angioimmunoblastic T-cell Lymphoma
- Fatigue Effect and Temperature Dependence in Luminescence of Disordered Silicide Layer Compound:Siloxene (Si_6H_3(OH)_3)
- High-Pressure Synthesis and Structures of New Barium Chromium Sulfides, BaCr_4S_7 and Ba_2Cr_5S_, with New Type Face-Sharing CrS_6 Structure Units
- A case of lymphoepithelioma-like carcinoma of the colon with ulcerative colitis
- Nuclear Magnetic Resonance Spectroscopic Study on the Grafting of Ethylene Oxide onto the Interlayer Surface of γ-Zirconium Phosphate
- Heat Capacities of H_2 and D_2 in Some Restricted Geometries : I. QUANTUM LIQUIDS AND SOLIDS : He in Restricted Geometry
- Heat Capacity Anomaly of Molecular Hydrogen Adsorbed in Interlayer Space of N^+(CH_3)_4-Montmorillonite
- Mucin-producing gallbladder adenocarcinoma with focal small cell and large cell neuroendocrine differentiation associated with pancreaticobiliary maljunction
- Does Water Liquid Phase Intrude into Hydrophobic Nanospaces of Alkyl-grafted Mesoporous Silica Immersed in Water? Detection by ^C CP-MAS NMR
- Synthesis of Solid Solutions in a System of LiCoO_2-Li_2MnO_3 for Cathode Materials of Secondary Lithium Batteries
- Effect of Vapor Adsorption on the Photoelectron Emission from Gold in Ambient Atmosphere
- Organic-Inorganic Cooperative Molecular Recognition in Nanostructure of Alkyl-grafted MCM-41
- The Formation of Hot Gaseous Haloes in Elliptical Galaxies with Massive Dark Haloes
- Endometrial adenocarcinoma without myometrial invasion metastasizing to the pancreas and masquerading as primary pancreatic neoplasm
- Functional Changes of Lysozyme by Conjugating with Carboxymethyl Dextran
- Synthesis and Properties of New Superconductors with Cage and Layered Structures
- Increased Hydrophobicity of Carboxymethyl Starch Film by Conjugation with Zein(Food & Nutrition Science)
- Oral Administration of Alginic Acid Oligosaccharide Suppresses IgE Production and Inhibits the Induction of Oral Tolerance
- Preparation of Monoclonal Antibody against Bovine β-Lactoglobulin and Its Unique Binding Affinity(Biological Chemistry)
- Oral Administration of Lactobacillus plantarum NRIC0380 Suppresses IgE Production and Induces CD4^+CD25^+Foxp3^+ Cells in Vivo
- Preparation and Structures of Lanthanoid Germanides, PrGe_, NdGe_, and TmGe_3 with Double Square Ge-Mesh Structures
- Thermal Expansion and Its Related Properties of Arsenic-Sulfur Glasses
- Primary sebaceous carcinoma of the tongue
- Polymerized Structure and Improved Physical and Biochemical Material Properties of Carboxymethyl Dextran-Conjugated Collagen
- Soft Textural and Emulsifiable Gelatin Formed by Conjugating with Fatty-Acylated Saccharide
- Reversible Thermal Transition of Soluble Branched Chains from Slightly Acid-treated Potato Starch
- Molybdenum Cluster Halide Compound Mo_6Cl_(OH_2)_2 with Six-Handed Linkage Hydrogen Bonding
- Superconductivity of Alkali Metal Intercalated Niobate with a Layered Perovskite Structure
- THERMAL EVOLUTION OF NICKEL CHLORITE-LIKE PHASE DERIVED FROM MONTMORILLONITE
- Improvement of the Physical Properties of Pepsin-Solubilized Elastin-Collagen Film by Crosslinking
- Regulation of T Cell Activation and Anergy by the Intensity of the Ca^ Signal in Cooperation with Other Signals
- Distinctly Different Sensitivity in the Induction and Reversal of Anergy of Th1 and Th2 Cells
- Functional Changes of Carboxymethyl Potato Starch by Conjugating with Amino Acids
- Effect of Swelling on the Superconducting Characteristics in Electron-Doped $\beta$-ZrNCl and HfNCl
- Feeding Behavior of the Green Rice Leafhopper, Nephotettix cincticeps (Homoptera: Cicadellidae) towards Pure Phloem Sap Collected from Resistant and Susceptible Rice Varieties
- Probing behavior of the brown planthopper, Nilaparvata lugens Stal (Homoptera:Delphacidae) on a non-host barnyard grass, and resistant and susceptible varieties of rice
- Functional Improvements in Food Proteins in Multiple Aspects by Conjugation with Saccharides : Case Studies of β-Lactoglobulin-Acidic Polysaccharides Conjugates
- Contribution of Charged Amino Acids to Improving the Degraded Viscosity of Potato Starch Paste by a Retort Treatment and during Storage
- Endowed Multi-functionality of Branched Oligosaccharide from Corn Starch by Phosphorylation and Oleylation
- Regulation of Collagen Matrix Reconstruction by Phosphated Polysaccharides
- β-Lactoglobulin Protects β-Ionone Related Compounds from Degradation by Heating,Oxidation, and Irradiation
- Thermal Diffusivity of Borate Glasses
- Introducing Site-Specific Glycosylation Using Protein Engineering Techniques Reduces the Immunogenicity of β-Lactoglobulin
- Induction of ALDH Activity in Intestinal Dendritic Cells by Lactobacillus plantarum NRIC0380
- Preparation and properties of ammonium hexachlorozirconate(IV) and its reaction with gaseous ammonia.
- Lactobacillus plantarun NRIC1832 Enhances IL-10 Production from CD4^+ T Cells in Vitro
- Cocurrent downflow bubble column with simultaneous gas-liquid injection nozzle.
- Co-Intercalation of Tetrahydrofuran and Propylene Carbonate with Alkali Metals in .BETA.-ZrNCl Layer Structured Crystal.
- Flow characteristics of three-phase fluidized bed with draft tube. Effect of outer column diameter and determination of gas-liquid interfacial area.
- 25pKE-2 PRESSURE-INDUCED STRUCTURAL TRANSFORMATION IN α-ZIRCONIUM NITRIDE CHLORIDE (ZrNCl)
- Synthesis of .BETA.-ZrClN by thermal decomposition of zirconium(IV) amide trichloride.
- Conversion of Brain-Specific Complex Type Sugar Chains by N-Acetyl-.BETA.-D-Hexosaminidase B.
- Changes in Functional Properties of Potato Starch by Oleylation Through Lipase-catalyzed Solid-phase Synthesis
- Enhanced Thermal Stability of Potato Starch by Compounding with Collagen Peptide and Cross-linking with Transglutaminase