Studies on Nitro Carboxylic Acids. III. The Reaction of α-Nitroolefins with Triethyl or Diethyl Phosphite

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概要

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• The reaction of α-nitroolefins with triethyl or diethyl phosphite was studied and structural assignment of the products was made by spectroscopic analyses. Ethyl α,β-unsaturated α-nitrocarboxylates (IV) and 1-nitroalkenes (V) reacted with triethyl phosphite to afford ethyl β-diethoxyphosphinyl-α,β-unsaturated-carboxylates (IX) and 2-diethoxyphosphinyl-1-alkenes (X), respectively. Compound (IV) reacted with diethyl phosphite to give ethyl β-diethoxyphosphinyl-α-nitrocarboxylates (VI). The geometrical isomerism in IX and the reaction mechanism were discussed.

• 公益社団法人 日本化学会の論文

著者

• Yonezawa Yasuchika

  Laboratory Of Oraganic Chemistry Faculty Of Engineering Kanagawa University

• Yoshimura Juji

  Laboratorium für Organische Chemie Technische Hochschule Tokyo

• Katayama Katsuhiro

  Laboratory of Organic Chemistry, Faculty of Engineering, Kanagawa University

• Shin Chung-gi

  Laboratory of Chemistry for Natural Products, Faculty of Science, Tokyo Institute of Technology

関連論文

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• .ALPHA.,.BETA.-Unsaturated carboxylic acid derivatives. XI. Convenient synthesis of tert-butyl 2-alkoxy- and hydroxy-2-acetylamino-3-mono- or 3,3-dihaloalkanoates.
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