Branched-chain Sugars. XXXV. The Synthesis of L-Rubranitrose (2,3,6-trideoxy-3-C-methyl-4-O-methyl-3-nitro-L-xylo-hexopyranose)

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概要

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• The title compound was stereoselectively synthesized from methyl 2,6-dideoxy-4-O-methyl-β-L-thero-hexopyranosid-3-ulose (11) through the successive conversions; cyanomesylation, reductive spiro aziridine formation, reductive ring-opening to the methyl-branched amino sugar, oxidation to the corresponding nitro sugar.

• 日本化学会の論文

著者

• 吉村 寿次

  Laboratory of Chemistry for Natural Products, Faculty of Science, Tokyo Institute of Technology

• Yoshimura Juji

  Laboratorium für Organische Chemie Technische Hochschule Tokyo

• 安盛 俊雄

  Laboratory of Chemistry for Natural Products, Faculty of Science, Tokyo Institute, of Technology

• Kondo Tatsuya

  Laboratory of Chemistry for Natural Products, Faculty of Science, Tokyo Institute of Technology

• Yasumori Toshio

  Laboratory of Chemistry for Natural Products, Faculty of Science, Tokyo Institute of Technology

関連論文

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• Branched-Chain Sugars. I. On the Configuration of Branched-Chain Derivatives of 1,2 : 5,6-Di-O-isopropylidene-α-D-ribo-hexofuranos-3-ulose
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