Synthesis of 2,2-Di-C-methyl-2-deoxy- and 4,4-Di-C-methyl-4-deoxypyranosides via Michael Addition of Conjugated Enopyranosiduloses
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概要
- 論文の詳細を見る
Three hexopyranosides having gem-di-C-methyl group at 2- or 4-positions were synthesized by Michael addition to 2-enopyranosid-4-ulose and 3-enopyranosid-2-ulose derivatives, respectively, followed by hydroboration. A heptopyranosid-6-ulose having gem-di-C-methyl group at C–4 was also synthesized from 4-enopyranosid-6-ulose derivative in a similar way.
- 日本化学会の論文
著者
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佐藤 憲一
Laboratory of Organic Chemistry, Faculty of Engineering, Kanagawa University
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吉村 寿次
Laboratory of Chemistry for Natural Products, Faculty of Science, Tokyo Institute of Technology
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Sato Ken-ichi
Laboratory of Chemistry for Natural Products, Faculty of Science, Tokyo Institute of Technology
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Hashimoto Hironobu
Laboratory of Chemistry of Natural Products, Faculty of Science, Tokyo Institute of Technology
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Kawauchi Nobuya
Laboratory of Chemistry of Natural Products, Faculty of Science, Tokyo Institute of Technology
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