Branched-chain Sugars. XIX. On the Application of 13C NMR Spectroscopy to the Configurational Assignment of 3-C-Substituents of Aldohexopyranose Derivatives
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概要
- 論文の詳細を見る
It was found that 13C NMR spectroscopy is applicable to the unequivocal configurational assignment at the quarternary carbon in seven pairs of 3-C-substituted-hexopyranose derivatives. The configuration of methyl 4,6-O-benzylidene-3-C-nitromethyl-2-O-p-tolylsulfonyl-α-D-glucopyranoside reported by Jordaan et al. is revised to D-allo by a chemical method.
- 日本化学会の論文
著者
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佐藤 憲一
Laboratory of Organic Chemistry, Faculty of Engineering, Kanagawa University
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Matsuzawa Masafumi
Laboratory of Chemistry for Natural Products, Faculty of Science, Tokyo Institute of Technology
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Sato Ken-ichi
Laboratory of Chemistry for Natural Products, Faculty of Science, Tokyo Institute of Technology
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Matsuzawa Masafumi
Laboratory of Chemistry for Natural Products, Faculty of Science, Tokyo Institute of Techgnology
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Ajisaka Katsumi
Laboratory of Chemistry for Natural Products, Faculty of Science, Tokyo Institute of Technology
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