Branched-chain Sugars. XXIX. Synthesis of Moenuronic Acid (4-C-Methyl-D-glucuronic Acid)
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概要
- 論文の詳細を見る
Moenuronic acid (4-C-methyl-D-glucuronic acid), a branched-chain sugar component of moenomycin A, was synthesized by the introduction of an axial C-methyl group into methyl 2,3-di-O-benzyl-6-O-trityl-α-D-xylo-hexopyranosid-4-ulose by the reaction with methyllithium, followed by deprotection and platinum-catalyzed oxidation of the C-6 position. Stereoselectivities in a few reactions for the introduction of C-methyl group were examined.
- 日本化学会の論文
著者
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SATO Ken-ichi
Laboratory of Molecular Biology, Biosignal Research Center, Kobe University
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佐藤 憲一
Laboratory of Organic Chemistry, Faculty of Engineering, Kanagawa University
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Kubo Kazusuke
Laboratory of Chemistry for Natural Products, Faculty of Science, Tokyo Institute of Technology
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Hong Namgi
Laboratory of Chemistry for Natural Products, Faculty of Science, Tokyo Institute of Technology
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Kodama Hisashi
Laboratory of Chemistry for Natural Products, Faculty of Science, Tokyo Institute of Technology
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Sato Ken-ichi
Laboratory of Chemistry for Natural Products, Faculty of Science, Tokyo Institute of Technology
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