Nuclear magnetic resonance studies of cobalt complexes. Cobalt-59 nuclear magnetic resonance spectrum of the hexakis(trimethyl phosphite)cobalt(III) complex.

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概要

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• The well-resolved septet spectrum was recorded for cobalt-59 NMR of [Co(P(OCH<SUB>3</SUB>)<SUB>3</SUB>)<SUB>6</SUB>](BF<SUB>4</SUB>)<SUB>3</SUB> in an acetonitrile solution. The obtained NMR parameters are: σ(Co-59)=+304 ppm (upfield from [Co(CN)<SUB>6</SUB>]<SUP>3−</SUP>), <SUP>1</SUP><I>J</I>(Co–P)=414 Hz, and Δ<I>H</I>(Co)=340 Hz.

• 公益社団法人 日本化学会の論文

著者

• Yamasaki Akira

  Department Of Chemistry Faculty Of Science The University Of Tokyo

• Fujiwara Shizuo

  Department Of Chemistry Faculty Of Science Chiba University

• Nakamura Keikichi

  Department of Chemistry, Faculty of Science, The University of Tokyo

• Aoyama Takashi

  Department of Chemistry, Faculty of Science, The University of Tokyo

• Yamasaki Akira

  Department of Applied Chemistry and Physics, The University of Electro-Communications

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