ESR study of hot ions in solid solutions of K2[(Zn,Cd,Hg)(CN)4].
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概要
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The ESR spectra of Cd(I) hot ions produced in solid solutions of K<SUB>2</SUB>[(Zn, Cd, Hg)(CN)<SUB>4</SUB>] indicate that there are paramagnetic species of hot-ion molecules characteristic of the single phase of K<SUB>2</SUB>[Zn(CN)<SUB>4</SUB>] and of the solid solution. The total contribution from the s and p orbitals to the spin density of the Cd(I) hot ions is constant, although the relative contributions from these two orbitals vary. It is shown that the mother lattice surrounding the hot ions determines the electronic structure and stability of the hot ions. These results suggest that the investigation of hot ions in a solid solution is useful for the study of microstructure of the solid solution.
- 公益社団法人 日本化学会の論文
著者
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Fujiwara Shizuo
Department Of Chemistry Faculty Of Science Chiba University
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Kozlowski Henryk
Department of Chemistry, Faculty of Science, The University of Tokyo
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Isoya Jun-ichi
Department of Chemistry, Faculty of Science, The University of Tokyo
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