Thermal Motion of Ammine Groups in Carbonatotetrammine Cobalt (III) by Proton Nuclear Magnetic Resonance
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概要
- 論文の詳細を見る
The broad-line NMR spectra of carbonatotetramminecobalt (III) bromide were observed in polycrystalline state at temperatures between 77°K and 383°K. It has been concluded that 1) form 200°K to 383°K the ammine groups are rotating about the Co-N axis, 2) there is no motion of the complex cation as a whole up to the decomposition point, and 3) below 90°K one of the four ammine groups in each complex becomes stationary.
- 社団法人日本物理学会の論文
- 1970-04-05
著者
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Yamasaki Akira
Department of Oral Pathology, Ohu University School of Dentistry
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FUJIWARA Shizuo
Department of Chemistry, Faculty of Science, Kanagawa University
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Arata Yoji
Department Of Chemistry Faculty Of Science The University Of Tokyo
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Yamasaki Akira
Department Of Chemistry Faculty Of Science The University Of Tokyo
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OKABE Masao
Department of Chemistry, Faculty of Science, The University of Tokyo
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Okabe Masao
Department Of Chemistry Faculty Of Science The University Of Tokyo
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Fujiwara Shizuo
Department Of Chemistry Faculty Of Science Chiba University
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Yamasaki Akira
Department of Applied Chemistry and Physics, The University of Electro-Communications
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