High resolution proton nuclear magnetic resonance studies of solute molecules in the poly(vinylalcohol) gel medium.
スポンサーリンク
概要
- 論文の詳細を見る
It was shown that a pair of spectra is observed for each solute in the medium of poly(vinylalcohol) gels swollen in water. Each of the spectra was assigned as originating from the solute in the PVA gel itself and that in the bulk solution surrounding the gel. It was concluded that the chemical shift difference is primarily explained in terms of the difference in the volume susceptibility of the PVA gel and the bulk solution. It was observed in the case of nicotinamide adenine dinucleotide (NAD) that the chemical shift differences are different for different functional groups. We suggest that this observation reflects a contribution from intermolecular interaction between PVA gel and the NAD molecule.
- 公益社団法人 日本化学会の論文
著者
-
Arata Yoji
Department Of Chemistry Faculty Of Science The University Of Tokyo
-
Fujiwara Shizuo
Department Of Chemistry Faculty Of Science Chiba University
-
Tanaka Michiko
Department Of Cell Regulation Medical Research Institute Tokyo Medical And Dental University
-
Fujikura Ryo
Department of Chemistry, Faculty of Science, The University of Tokyo
-
Ogino Takashi
Department of Chemistry, Faculty of Science, The University of Tokyo
-
Tanaka Michiko
Department of Chemistry, Faculty of Science, The University of Tokyo
関連論文
- Treatment for Locally Advanced Esophageal Carcinoma Complicated by Fistulas: Case Report
- Relationship Between the s-wave Amplitude of the Multifocal Electroretinogram and the Retinal Nerve Fiber Layer Thickness in Glaucomatous Eyes
- Choroidal Circulatory Disturbance in Ocular Sarcoidosis Without the Appearance of Retinal Lesions or Loss of Visual Function
- Relative Biological Effectiveness of the 235 MeV Proton Beams at the National Cancer Center Hospital East
- Echo Free Space in Morrison's Pouch in a Patient with Traumatic Bladder Rupture : A Case Report
- Usefulness of Multidetector Computed Tomography(M DCT) for the Initial Evaluation of Multiple Blunt Trauma of the Trunk
- Sub-acute Toxicosis Caused by a Multiple Doses Tegafur/Uracil (UFT) for Suicide : A Case Report
- Non-Biological Complete Differentiation of Enantiomeric Isomers of Amino Acids and Sugers
- Adenoid Cystic Carcinoma of the Tracheobronchial System : The Role of Postoperative Radiotherapy
- Measurement of Electromagnetic Fields in Space by Antenna Effect of Human Bodies. A Study of Safety Control and Risk Management
- Intravital observation of T-lymphocytes in the colonic microcireulation
- Effects of pCO_2 on the CSF Turnover Rate in Rats Monitored by Gd-DTPA Enhanced T_1-Weighted Magnetic Resonance Imaging
- Development of a Monoclonal Antibody against Epstein-Barr Virus Nuclear Antigen Leader Protein (EBNA-LP) That Can Detect EBNA-LP Expressed in P3HR1 Cells
- Bilateral Internal Mammary Artery Injury without Fracture of the Chest Following a Traffic Accident
- Thermal Motion of Ammine Groups in Carbonatotetrammine Cobalt (III) by Proton Nuclear Magnetic Resonance
- Nonbiological Complete Differentiation of the Enantiomeric Isomers of Amino Acids and Sugars by the Complexes of Gases with the Eutectic Compounds of Alkali Chlorides and Water
- Lateral diffusion of manganese in the rat brain determined by T_1 relaxation time measured by ^1H MRI
- Transition Metal-catalyzed Asymmetric Vinylcyclopropane-Cyclopentene Rearrangements with Chiral Phosphine Ligands. Dramatic Solvent Effects on Asymmetric Induction
- Superfine Particle Magnetite
- Aerodynamic Noise Radiation from a Circular Cutting Tool : Effect of Slit on Aerodynamic Noise Reduction
- TRIGGERING OF ION SELECTIVE ELECTRODE
- Analysis of the NMR Spectra of Acrylic Acid and Ethyl Acrylate
- E-2-3 An N.M.R. Study of Amino Acids(Mainly physico-chemical methods)
- One Aspect of Analytical Chemistry in Old East and West (〔日本分析化学会〕創立30周年特別記念号)
- Solvent Shift of Methyl Proton Nuclear Magnetic Resonance
- Ab Initio Calculation of Capacitance of Semi-Infinite Jellium Electrodes with a Nanoscale Gap
- ab initio Calculation of Capacitance of Nanostructures
- Proton and Nitrogen-14 Nuclear Magnetic Resonance Study of Pyridine - Water System
- Spectral smoothing in correlation NMR spectroscopy.
- Proton magnetic resonance study of interaction between penicillin G and hen egg white lysozyme.
- High resolution proton nuclear magnetic resonance studies of solute molecules in the poly(vinylalcohol) gel medium.
- 1H NMR study of dissociation and re-association of apoferritin and ferritin.
- Dynamic calibration and memory effect for fluoride ion selective electrode.
- Fourier Analysis of Alternating Current Polarography: Amplitude and Phase of Fundamental and Second Harmonic AC Polarographic Waves
- Fourier Analysis of AC Polarography. Elimination of Non-Faradaic Effects and Determination of Kinetic Parameters for Cd(II)-Na2SO4 System
- ESR study of .GAMMA.-ray irradiated potassium hexacyanocobaltate K3(Co(CN)6).
- Conformational study of glutathione by NMR.
- The solvent extraction of alkali metal picrates by benzo-15-crown-5.
- ESR study of hot ions in solid solutions of K2[(Zn,Cd,Hg)(CN)4].
- A quantum chemical study on the ion influence on linear water polymer.
- Nuclidic Mass Measurement by Ion Cyclotron Resonance
- The determination of the critical volume for the free motion of solute entities in an aqueous solution.
- Super High Sensitivity of CuSe–Ag2S Solid Membrane Copper(II) Ion Selective Electrode in Several Metal Buffer Solutions
- Computer-assisted In-phase AC Polarography: Determination of Cadmium (II) Ions
- Fourier Analysis of AC Polarogaphy: Kinetic Parameters for Zn(II)-1 M NaClO4 and KCl Systems
- Electrode reactions of several transition metal ions in aqueous polyelectrolyte solutions as studied by DC and Fourier transform polarography.
- Electron Spin Resonance and Cell Division in Silkworm Egg
- NMR study of spontaneous degradation of penicillin G in aqueous solution.
- Nuclear magnetic resonance studies of cobalt complexes. Cobalt-59 nuclear magnetic resonance spectrum of the hexakis(trimethyl phosphite)cobalt(III) complex.
- Cobalt-59 Nuclear Magnetic Resonance Study of Cobalt(III) Complexes. Empirical Rules for the Cobalt-59 Chemical Shifts and Line Widths of [CoIII(en)x(NH3)6−2x−yLy]-type Com
- A Polarographic Study of Amino Acids in Aqueous Solution
- Proton magnetic relaxation time T1 of water in acrylamide gel.
- The solvent extraction of silver and thallium(I) picrates by crown ethers.
- Thermodynamic study for complexation reactions of dibenzo-24-crown-8 with alkali metal ions in acetonitrile.
- An interpretation of the "Molecular space" on the basis of quantum chemical calculations of hydrated ions.
- The Polarographic Reduction of [Pd(oxine)2] and [Pd(acac)2] in a N,N-Dimethylformamide Solution
- Classification of Polarographic Current-Potential Curves of Inorganic Anions as a Function of Reduction Potentials
- Algorithm of data processing in correlation NMR spectroscopy.
- 1H NMR study of interaction of probe molecules with the phosphate ion on the iron core of horse spleen ferritin.