An interpretation of the "Molecular space" on the basis of quantum chemical calculations of hydrated ions.
スポンサーリンク
概要
- 論文の詳細を見る
Quantum chemical calculation has been made for the sizes of the hydration shells of the metal ions as well as for the binding energies of water molecules in the hydration shells. The results of the both calculations give the basis of the size of the molecular space. Although the experimental value of the molecular space, (20±5A)<SUP>3</SUP>, does not exactly agree with the calculated value, we assume that the quantum chemically obtained hydration sphere refers to the molecular space.
- 公益社団法人 日本化学会の論文
著者
-
Fujiwara Shizuo
Department Of Chemistry Faculty Of Science Chiba University
-
Rode Bernd
Department of Chemistry, Faculty of Science, The University of Tokyo
関連論文
- Non-Biological Complete Differentiation of Enantiomeric Isomers of Amino Acids and Sugers
- Measurement of Electromagnetic Fields in Space by Antenna Effect of Human Bodies. A Study of Safety Control and Risk Management
- Thermal Motion of Ammine Groups in Carbonatotetrammine Cobalt (III) by Proton Nuclear Magnetic Resonance
- Nonbiological Complete Differentiation of the Enantiomeric Isomers of Amino Acids and Sugars by the Complexes of Gases with the Eutectic Compounds of Alkali Chlorides and Water
- Superfine Particle Magnetite
- TRIGGERING OF ION SELECTIVE ELECTRODE
- Analysis of the NMR Spectra of Acrylic Acid and Ethyl Acrylate
- E-2-3 An N.M.R. Study of Amino Acids(Mainly physico-chemical methods)
- One Aspect of Analytical Chemistry in Old East and West (〔日本分析化学会〕創立30周年特別記念号)
- Solvent Shift of Methyl Proton Nuclear Magnetic Resonance
- Proton and Nitrogen-14 Nuclear Magnetic Resonance Study of Pyridine - Water System
- Proton magnetic resonance study of interaction between penicillin G and hen egg white lysozyme.
- High resolution proton nuclear magnetic resonance studies of solute molecules in the poly(vinylalcohol) gel medium.
- 1H NMR study of dissociation and re-association of apoferritin and ferritin.
- Dynamic calibration and memory effect for fluoride ion selective electrode.
- Fourier Analysis of Alternating Current Polarography: Amplitude and Phase of Fundamental and Second Harmonic AC Polarographic Waves
- Fourier Analysis of AC Polarography. Elimination of Non-Faradaic Effects and Determination of Kinetic Parameters for Cd(II)-Na2SO4 System
- ESR study of .GAMMA.-ray irradiated potassium hexacyanocobaltate K3(Co(CN)6).
- Conformational study of glutathione by NMR.
- The solvent extraction of alkali metal picrates by benzo-15-crown-5.
- ESR study of hot ions in solid solutions of K2[(Zn,Cd,Hg)(CN)4].
- A quantum chemical study on the ion influence on linear water polymer.
- Nuclidic Mass Measurement by Ion Cyclotron Resonance
- The determination of the critical volume for the free motion of solute entities in an aqueous solution.
- Super High Sensitivity of CuSe–Ag2S Solid Membrane Copper(II) Ion Selective Electrode in Several Metal Buffer Solutions
- Computer-assisted In-phase AC Polarography: Determination of Cadmium (II) Ions
- Fourier Analysis of AC Polarogaphy: Kinetic Parameters for Zn(II)-1 M NaClO4 and KCl Systems
- Electrode reactions of several transition metal ions in aqueous polyelectrolyte solutions as studied by DC and Fourier transform polarography.
- Electron Spin Resonance and Cell Division in Silkworm Egg
- NMR study of spontaneous degradation of penicillin G in aqueous solution.
- Nuclear magnetic resonance studies of cobalt complexes. Cobalt-59 nuclear magnetic resonance spectrum of the hexakis(trimethyl phosphite)cobalt(III) complex.
- Cobalt-59 Nuclear Magnetic Resonance Study of Cobalt(III) Complexes. Empirical Rules for the Cobalt-59 Chemical Shifts and Line Widths of [CoIII(en)x(NH3)6−2x−yLy]-type Com
- A Polarographic Study of Amino Acids in Aqueous Solution
- Proton magnetic relaxation time T1 of water in acrylamide gel.
- The solvent extraction of silver and thallium(I) picrates by crown ethers.
- Thermodynamic study for complexation reactions of dibenzo-24-crown-8 with alkali metal ions in acetonitrile.
- An interpretation of the "Molecular space" on the basis of quantum chemical calculations of hydrated ions.
- The Polarographic Reduction of [Pd(oxine)2] and [Pd(acac)2] in a N,N-Dimethylformamide Solution
- Classification of Polarographic Current-Potential Curves of Inorganic Anions as a Function of Reduction Potentials
- 1H NMR study of interaction of probe molecules with the phosphate ion on the iron core of horse spleen ferritin.