The Polarographic Reduction of [Pd(oxine)<SUB>2</SUB>] and [Pd(acac)<SUB>2</SUB>] in a <I>N</I>,<I>N</I>-Dimethylformamide Solution
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概要
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Palladium(I) species were produced by the polarographic reduction of palladium(II)–oxinate and –acetylacetonate complexes in a <I>N</I>,<I>N</I>-dimethylformamide solution. These species were unstable and decomposed into electro-inactive species through an irreversible following chemical reaction. The rate constants were obtained from the fundamental and second harmonic AC polarograms, which were obtained at two different frequencies of the AC potential, 55.8 and 173.6 Hz, at 22.5 °C as 5.5±1.0 s<SUP>−1</SUP> for the oxinate complex and as 50±10 s<SUP>−1</SUP> for the acetylacetonate complex.
- 公益社団法人 日本化学会の論文
著者
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Fujiwara Shizuo
Department Of Chemistry Faculty Of Science Chiba University
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Hirota Michio
Department of Chemistry, Faculty of Science, The University of Tokyo
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