A systmeatic study of the yields of .GAMMA.-radiolysis products in C1, C2, and C3-chlorofluorocarbons.
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概要
- 論文の詳細を見る
In the presence of bromine as a scavenger, the yields of the radiolysis products in eleven kinds of C<SUB>1</SUB>–C<SUB>3</SUB> chlorofluorocarbons were investigated by means of gas chromatography. The <I>G</I>-values for the rupture of bonds in radiolysis were found to correlate with the halogen composition and the structure of their molecules. The <I>G</I>-values for the C–Cl (or C–F) bond rupture generally appear to increase with the number of chlorine (or fluorine) atoms in the chlorofluorocarbons; there was a marked difference between the <I>G</I>-values for the C–Cl rupture in each pair of structural isomers of chlorofluoroethanes. A striking selectivity in bond rupture was observed between the two C–C bonds in the chlorofluoropropanes.
- 公益社団法人 日本化学会の論文
著者
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Makide Yoshihiro
Department Of Chemistry Faculty Of Science The University Of Tokyo
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Tominaga Takeshi
Department Of Chemistry Faculty Of Science The University Of Tokyo
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Aoyama Takashi
Department of Chemistry, Faculty of Science, The University of Tokyo
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Fukumizu Takefumi
Department of Chemistry, Faculty of Science, The University of Tokyo
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Okuda Akihiko
Department of Chemistry, Faculty of Science, The University of Tokyo
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