Infrared Spectra of Cyclohexanoxime and Cyclohexanoxime-<I>d</I>

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概要

• 論文の詳細を見る

• The infrared absorption bands due to the functional group of cyclohexanoxime and cyclohexanoxime-<I>d</I> were reasonably assigned by taking into account the concentration dependence of these bands in solutions. Cyclohexanoxime having no conjugate system showed a spectral feature different in many respects from that of diacetyl monoxime or isonitrosoacetone already studied. The type of hydrogen bonding is －OH…N=C< both in solutions and in the solid state. Consequently, the stretching frequency of bonded OH groups of cyclohexanoxime is different from those of diacetyl monoxime and isonitosoacetone. The doubling of absorption bands was observed for both the OH in-plane bending vibration and the NO stretching vibration of free molecules. This suggests the presence of rotational isomers. The wave numbers of the C=N stretching vibration is higher, while that of the NO stretching vibration is lower than those of the corresponding vibrations of diacetyl monoxime and isonitrosoacetone. This indicates that the double bond character of the C=N bond in cyclohexanoxime is greater than that in oximes having a conjugate system.

• 社団法人 日本化学会の論文

著者

• KIMURA M.

  Department of Obstetrics and Gynecology, Toranomon Hospital

• Yamamoto Osamu

  Department Of Applied Chemistry Kanagawa Institute Of Technology

• Kuroda Yoko

  Department Of Neuropsychiatry Osaka City University Medical School

• Kubo Masaji

  Department of Chemistry Nagoya University

• Kimura Masao

  Department of Chemistry Nagoya University

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