The Molecular Structure of Tin Tetrachloride as Determined by Gas-electron Diffraction

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概要

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• The molecular structure of tin tetrachloride was determined by the sector-microphotometer method of gas-electron diffraction. By taking into account the phase-shift for the Sn-Cl pair, the following results were obtained: the tetrahedral structure with <I>r<SUB>g</SUB></I>(Sn–Cl)=2.280<SUB>8</SUB>±0.003<SUB>7</SUB> Å, <I>l</I>(Sn–Cl)=0.049<SUB>9</SUB>±0.003<SUB>3</SUB> Å, and <I>l</I>(Cl···Cl)=0.108<SUB>6</SUB>±0.005<SUB>0</SUB> Å. These values, especially that of the mean amplitude, <I>l</I>(Sn–Cl), are different from those previously reported by other workers. This is because the effect of the phase shift was neglected in the previous investigations.

• 公益社団法人 日本化学会の論文

著者

• Kimura Masao

  Department of Chemistry Nagoya University

• Fujii Hideji

  Department of Chemistry, Faculty of Science, Hokkaido University

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