Molecular Structure and Phase-shift of Tetramethyllead as Studied by Gas Electron Diffraction

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概要

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• The molecular structure of tetramethyllead has been determined by the sector-microphotometer method of gas-phase electron diffraction. The structure parameters determined by a least-squares analysis on molecular intensities are, with estimated limits of error, as follows; <I>r<SUB>g</SUB></I>(Pb–C)=2.238±0.009 Å, <I>r<SUB>g</SUB></I>(Pb–H)=2.72±0.06 Å, <I>r<SUB>g</SUB></I>(C···C)=3.66±0.07 Å, and <I>r<SUB>g</SUB></I>(C–H)=1.08±0.02 Å. The experimental cut-off point was nearly 37 in <I>q</I> value for the 42.0 keV electrons; this was not in sufficient agreement with the theoretical value as calculated from the Thomas-Fermi-Dirac potential for Pb and from the Hartree-Fock potential for C. Moreover, the experimental background showed a significant deviation from its theoretical counterpart in the region of small <I>q</I> values. This discrepancy has not been accounted for even by the use of scattering factors based on a relativistic SCF calculation, or by the correction for the polarization effect available at present.

• 公益社団法人 日本化学会の論文

著者

• Iijima Takao

  Department Of Chemistry Faculty Of Science Gakushuin University

• Kimura Masao

  Department of Chemistry Nagoya University

• Oyamada Takeo

  Department of Chemistry, Faculty of Science, Hokkaido University

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