Electron Diffraction Investigation of Gaseous Mercury(II) Chloride

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概要

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• The molecular structure of mercury (II) chloride has been determined by the sector-microphotometer method of gas-phase electron diffraction at accelerating voltages of 29 and 42 kV. The parameter values obtained are: <I>r<SUB>g</SUB></I>(Hg–Cl), 2.252±0.005 Å; <I>l</I>(Hg–Cl), 0.052±0.005 Å; <I>r<SUB>g</SUB></I>(Cl–Cl), 4.48±0.04 Å; and <I>l</I>(Cl–Cl), 0.09±0.04 Å. A linear structure has been confirmed within an error of 16°. The experimental mean amplitudes are consistent with the estimated values based on the spectroscopic data. No appreciable differences in the structure parameters have been found between the results of analysis carried out on the basis of the Thomas-Fermi-Dirac and the relativistic Hartree-Fock-Slater scattering factors.

• 公益社団法人 日本化学会の論文

著者

• Konaka Shigehiro

  Department Of Chemistry Faculty Of Science Hokkaido University

• Kimura Masao

  Department of Chemistry Nagoya University

• Kashiwabara Kuniaki

  Department of Chemistry, Faculty of Science, Hokkaido University

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