Magnetic Susceptibility of Magnesium 2,2′-Dipyridylide in its THF Adducts

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概要

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• The magnetic susceptibility of magnesium 2,2′-dipyridylide has been determined in its THF (tetrahydrofuran) adducts in a temperature range of 1.6–20 K. The susceptibility of Mg(dipy)<SUB>2</SUB>.THF exhibits two maxima at about 3.9 and 9.5 K due to short range and long-range interactions, respectively. The observed susceptibility conforms to the alternating linear Heisenberg model above about 6 K. Mg(dipy)<SUB>2</SUB>·3THF shows no definite maximum of magnetic susceptibility. The magnetic behavior of these complexes different from that of Be(dipy)<SUB>2</SUB> is attributable to the difference in the ionic character between Mg–N and Be–N bonds.

• 公益社団法人 日本化学会の論文

著者

• Kubo Masaji

  Department of Chemistry Nagoya University

• Hara Ken-ichi

  Department of Chemistry, Faculty of Science, Nagoya University

• Inoue Motomichi

  Department of Chemistry and Department of Physics, Faculty of Science, Nagoya University

• Horiba Tatsuo

  Department of Chemistry, Faculty of Science, Nagoya University

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