EFFECT OF THE SURFACE POTENTIAL ON THE CATION EXCHANGE CAPACITY OF KAOLIN MINERALS
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概要
- 論文の詳細を見る
The characteristics related to surface charge were investigated for various kind of kaolin minerals.Two types of kaolin minerals were used, one from weathering and sedimentary origins, Shinagawa-kibushi and Hara-gairome, and the other from hydrothermal origins, Georgia-kaolin and dickite.They were chemically treated in order to remove the organic species and ion-exchanged with Na^+.The surface potential obtained from the variation of zeta potential and the cation exchange capacity(CEC)were studied for neutral kaolin minerals.A positive correlation exists between the surface potential and the CEC, and the CEC depends directly on the surface potential on the particle.The surface potential was larger for clays of weathering and sedimentary origins, Shinagawa-kibushi and Hara-gairome, than that of the hydrothermal originated Georgia-kaolin and dickite.The surface poteintial among kaolin minerals depends on the thickness of the edge plane and increases with a decrease in the crystallite size.Therefore, Shinagawa-kibushi and Hara-gairome which have large surface potential, have a large water film thickness due to the large amount of absorbed cations.
- 日本粘土学会の論文
著者
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山本 治
Department of Chemistry, Faculty of Engineering, Mie University
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TAKEDA Yasuo
Department of Chemistry, Mie University
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山本 治
三重大工
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YAMAMOTO Osamu
Department of Applied Chemistry, Kanagawa Institute of Technology
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Yamamoto O
Aichi Inst. Technol. Toyota Jpn
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TONE KISATO
Department of Chemistry for Materials, Faculty of Engineering, Mie University
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KAMORI MASANOBU
Toyo Denka Kogyo Co.Ltd.
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SHIBASAKI YASUO
National Industrial Research Institute of Nagoya
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Takeda Yasuo
Department Of Cardiac Surgery Kyusyu University School Of Medicine
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Takeda Yasuo
Department Of Chemistry For Materials Faculty Of Engineering Mie University
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山本 治
三重大学 工学部
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Tone Kisato
Department Of Chemistry For Materials Faculty Of Engineering Mie University
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Yamamoto Osamu
Department Of Chemistry Faculty Of Engineering Mie University
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Yamamoto Osamu
Department Of Applied Chemistry Kanagawa Institute Of Technology
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