Modified Kinetic Model for Dichloropropanol Synthesis from Glycerin And Anhydrous Hcl at High Pressure
スポンサーリンク
概要
- 論文の詳細を見る
A modified kinetic model for the synthesis of dichloropropanol (DCP) from glycerin and anhydrous HCl has been proposed for high-pressure reactions with a fixed weight ratio of glycerin to acetic acid by considering the volume change arising from the generation of water during the reaction. The yield of DCP was found to be maximized at 130°C and 6 bar. The modified kinetic parameters and high-pressure reaction model were evaluated by high-accuracy fitting to experimental data. The results allowed the creation of a kinetic model suitable for application to DCP synthesis from glycerin and anhydrous HCl at high pressures.
著者
-
Bae Jong
Department Of Chemical Engineering And School Of Environmental Engineering Pohang University Of Scie
-
Lee Dong
Department Of Biotechnology College Of Natural Science Dongguk University
-
Lim Jong
Department Of Advanced Materials Science And Engineering Sungkyunkwan University
-
SONG Won
Production Technology Center, Samsung Fine Chemicals Co. Ltd.
-
KWON Myeong
Production Technology Center, Samsung Fine Chemicals Co. Ltd.
-
WOO Sung
Production Technology Center, Samsung Fine Chemicals Co. Ltd.
-
SUNG Su
Department of Chemical Engineering, Kyungpook National University
関連論文
- Proteomic Analysis of Bronchoalveolar Lavage Fluid Obtained from Rats Exposed to Formaldehyde
- Characteristics of Multi-Stage Porous Plate Precipitator with Water Spray System
- Multiple myeloma in Korea : past, present, and future perspectives. Experience of the Korean Multiple Myeloma Working Party
- Parietal Lobe Epilepsy : The Semiology, Yield of Diagnostic Workup, and Surgical Outcome
- FDG-PET Images Quantified by Probabilistic Atlas of Brain and Surgical Prognosis of Temporal Lobe Epilepsy
- Characteristics of Organic Light-Emitting Devices by the Surface Treatment of Indium Tin Oxide Surfaces Using Atmospheric Pressure Plasmas
- Binocularity and spatial frequency dependence of calcarine activation in two types of amblyopia
- Stress-Driven Formation of InGaAs Quantum Dots on GaAs with Sub-Micron Platinum Pattern
- Clinical course of non-severe aplastic anemia in adults
- High Efficiency White Organic Light-Emitting Diodes from One Emissive Layer
- Effect of Indium-Oxide Deposited Using an Oxygen Ion-Beam-Assisted-Deposition to Top-Emitting Organic Light-Emitting Diodes
- 970. 韓国 Youngwol からのオルドビス紀 (Llanvirnian) 層孔虫
- Antimutagenicity and Cytotoxicity of the Constituents from the Aerial Parts of Rumex acetosa(Pharmacognosy)
- The clinical impact of ^F-FDG PET in papillary thyroid carcinoma with a negative ^I whole body scan : a single-center study of 108 patients
- Correlation between serum CEA level and metabolic volume as determined by FDG PET in postoperative patients with recurrent colorectal cancer
- Non-A type nucleophosmin 1 gene mutation predicts poor clinical outcome in de novo adult acute myeloid leukemia : differential clinical importance of NPM1 mutation according to subtype
- Bacterial DNA Containing Methylated CpG Motifs Retains Immunostimulatory Activity in Synergy with Modified Lipopolysaccharides
- Enzyme Replacement Therapy in a Case of Atypical Infantile Onset Pompe Disease
- Conduction Behavior of SrBi_2Ta_2O_9 Thin Film Grown by Pulsed Laser Deposition
- CW-270033, a Novel Pyrrolidinyl-thio Carbapenem, Has Potent Antimicrobial Activity in Vitro and in Vivo(Miscellaneous)
- Antimutagenic Constituents from the Thorns of Gleditsia sinensis
- Inhibitory Effects of the Essential Oil from SuHeXiang Wan on the Central Nervous System after Inhalation (Pharmacology)
- Effect of Carbon and Sulfur in Continuously Cast Strand on Longitudinal Surface Cracks
- Inhibitory Effects of the Fragrance Inhalation of Essential Oil from Acorus gramineus on Central Nervous System
- Modulation of Radioligand Binding to the GABA_A-benzodiazepine Receptor Complex by a New Component from Cyperus Rotundus
- Extramedullary Relapse Confirmed by Fluorescence In Situ Hybridization Study of an Ear Mass in Acute Promyelocytic Leukemia
- Residual Stress Behavior of Polyimide Thin Films : Effect of Precursors
- Infrared plus visible light and heat from natural sunlight participate in the expression of MMPs and type I procollagen as well as infiltration of inflammatory cell in human skin in vivo
- Occipital Lobe Epilepsy : Clinical Characteristics, Surgical Outcome, and Role of Diagnostic Modalities
- Cancer screening using ^F-FDG PET/CT in Korean asymptomatic volunteers : a preliminary report
- Maximal safe dose of I-131 after failure of standard fixed dose therapy in patients with differentiated thyroid carcinoma
- Comparison of FDG-PET findings of brain metastasis from non-small-cell lung cancer and small-cell lung cancer
- Superiority of HMPAO Ictal SPECT to ECD Ictal SPECT in Localizing the Epileptogenic Zone
- Diagnostic Performance of [^F]FDG-PET and Ictal [^Tc]-HMPAO SPECT in Occipital Lobe Epilepsy
- The effect of tumor size on F-18-labeled fluorodeoxyglucose and fluoroerythronitroimidazole uptake in a murine sarcoma model
- Bone Scan Appearance of Renal Osteodystrophy in Diabetic Chronic Renal Failure Patients
- Time-Course Changes of Hormones and Cytokines by Lipopolysaccharide and Its Relation with Anorexia
- Detection of the BCR-ABL Gene by Interphase Fluorescence In Situ Hybridization (iFISH) in Chronic Myelogenous Leukemia Patients after Hemopoietic Stem Cell Transplantation: The Feasibility of iFISH Monitoring of Therapeutic Response in Peripheral Blood
- Antimutagenic Activity of 5α-Cholest-7-en-3β-ol, a New Component from the Starfish Asterina pectinifera
- The molecular basis of phenylketonuria in Koreans
- IS-2 The effects of leptin on in vitro development of mouse embryos(Group1 Reproduction1,International Session)
- Liquid-phase Hydrodechlorination of CCl_4 with Co-production of Diethylcarbonate and Acetal
- A Novel Method of CCI_4 Disposal by Disproportionation with CH_4 over Pt on Various Supports
- Stevens-Johnson syndrome following occupational exposure to carbamate insecticide
- Comparison of the efficacy and safety of different formulations of omeprazole-based triple therapies in the treatment of Helicobacter pylori-positive peptic ulcer
- Ion chromatography detector based on solid-state ion-selective electrode array
- A Case of Acral Melanocytic Hyperplasia : A Unique Pigmented Lesion Mimicking Acral Lentiginous Melanoma In situ
- Identification and functional analysis of cystathionine beta-synthase gene mutations in patients with homocystinuria
- Prediction of Furnace Heat Transfer and Its Influence on the Steel Slab Heating and Skid Mark Formation in a Reheating Furnace
- Modified Kinetic Model for Dichloropropanol Synthesis from Glycerin And Anhydrous Hcl at High Pressure
- P-2 A Study for Root Shape and Welding Procedure of Welded Joint with Backing Strip(Poster Session,SIMAP'88 Proceedings of International Symposium on Strategy of Innovation in Materials Processing-New Challenge for the 21st Century-)
- Design of Composite Hip Prostheses Considering the Long-Term Behavior of the Femur
- Serum Cystatin C Is Related to Pulse Wave Velocity Even in Subjects with Normal Serum Creatinine
- Can γ-Glutamyltransferase be an Additional Marker of Arterial Stiffness?
- S-Phase Accumulation of Candida albicans by Anticandidal Effect of Amentoflavone Isolated from Selaginella tamariscina(Medicinal Chemistry)
- Global Asymptotic Stabilization of a Class of Nonlinear Time-Delay Systems by Output Feedback(Systems and Control)
- Systemic Plasmacytosis : A Case which Improved with Melphalan
- A stability analysis of tandem offloading systems at sea
- Solitary Milialike Idiopathic Calcinosis Cutis : A Case Unassociated with Down Syndrome
- Reversible Thermochromic Change of Molecular Architecture for a Diacetylene Derivative 10,12-Pentacosadiynoic Acid Self-assembled Thin Films on Ag Surfaces
- Variation of Facial Psysiological Parameters According to Mental Stress
- Various strategies for highly-efficient two-photon absorption in porphyrin arrays
- Inactivation of the PTEN gene protein product is associated with the invasiveness and metastasis, but not angiogenesis, of breast cancer
- An Experimental Study of Thermal-hydraulic Phenomena in the Downcomer with a Direct Vessel Injection System of APR1400 during the LBLOCA Reflood Phase
- Assessment of an Ultrasonic Sensor and a Capacitance Probe for Measurement of Two-phase Mixture Level
- Ex Vivo Expansion of Human Umbilical Cord Blood CD34+ Cells in a Collagen Bead-Containing 3-Dimensional Culture System
- Fabrication of W_2NiB_2-Ni Borides Cermets
- Induction of Apoptosis by Cordyceps militaris through Activation of Caspase-3 in Leukemia HL-60 Cells(Molecular and Cell Biology)
- Induction of Apoptosis by Disturbing Mitochondrial-Membrane Potential and Cleaving PARP in Jurkat T Cells through Treatment with Acetoxyscirpenol Mycotoxins(Molecular and Cell Biology)
- Extraforaminal Lumbar Synovial Cyst Causing Sudden Foot Drop
- Erythema Induratum with Pulmonary Tuberculosis : Report of Three Cases
- Effective Screening Medium for the Biodegradation of Oleic Acid by Aspergillus niger
- Plasma Characteristics of 450 mm Diameter Ferrite-Enhanced Inductively Coupled Plasma Source
- The Molecular Basis of Phenylketonuria in Koreans
- Risk Factors for Perioperative Cardiac Complications After Lumbar Fusion Surgery
- Chromatin-based regulation of cytokine transcription in T_h2 cells and mast cells
- Adjacent Segment Disease After Interbody Fusion and Pedicle Screw Fixations for Isolated L4-L5 Spondylolisthesis : A Minimum Five-Year Follow-up
- Handover Control Method Using Resource Reservation in Mobile Multimedia Networks
- Simultaneous quantification of rosiglitazone and its two major metabolites, N-desmethyl and p-hydroxy rosiglitazone in human plasma by liquid chromatography/tandem mass spectrometry : Application to a pharmacokinetic study
- Inflammatory Nodules of the Lower Legs : A Clinical and Histological Analysis of 134 Cases in Korea
- Efficient Generation of Cube-on-Face Crystallographic Texture in Iron and its Alloys
- The c.3040C > T mutation in COL1A1 is recurrent in Korean patients with infantile cortical hyperostosis (Caffey disease)
- In Vitro Antimicrobial Activity and the Mode of Action of Indole-3-Carbinol against Human Pathogenic Microorganisms(Microbiology)
- Capillary gas chromatographic determination of proteins and biological amino acids as N(O)-tert.-butyldimethylsilyl derivatives
- Mechanism of Decreased Susceptibility for Gram-negative Bacteria and Synergistic Effect with Ampicillin of Indole-3-carbinol(Microbiology)
- The Combination Effect of Korean Red Ginseng Saponins with Kanamycin and Cefotaxime against Methicillin-Resistant Staphylococcus aureus(Microbiology)
- Drying Characteristics of Fine Powders in an Inert Medium Circulating Fluidized Bed
- Models for Minimum Liquid Fluidization Velocity of Gas-Liquid Fluidized Beds
- Properties of NLC Graph Languages squeezed with Bipartite Graphs
- Folliculosebaceous cystic hamartoma on the nipple
- Modified Kinetic Model for Dichloropropanol Synthesis from Glycerin and Anhydrous HCl at High Pressure
- Plasma Characteristics of Large Area Inductively Coupled Plasma System Using Ferrite-Module-Enhanced U-Type Antenna
- Effect of DC Bias Voltage on the Characteristics of Low Temperature Silicon–Nitride Films Deposited by Internal Linear Antenna Inductively Coupled Plasma Source
- Characteristics of Internal Inductively Coupled Plasma Source for Ultralarge-Area Plasma Processing
- Fast Pyrolysis of Biomasses in a Bubbling Fluidized Bed Reactor
- Characteristics of a Multilayer SiOx(CH)yNz Film Deposited by Low Temperature Plasma Enhanced Chemical Vapor Deposition Using Hexamethyldisilazane/Ar/N2O
- Deposition of SiO2 by Plasma Enhanced Chemical Vapor Deposition as the Diffusion Barrier to Polymer Substrates
- Study on the O2 Plasma Treatment of Indium Tin Oxide for Organic Light Emitting Diodes Using Inductively Coupled Plasma