Modified Kinetic Model for Dichloropropanol Synthesis from Glycerin and Anhydrous HCl at High Pressure

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概要

• 論文の詳細を見る

• A modified kinetic model for the synthesis of dichloropropanol (DCP) from glycerin and anhydrous HCl has been proposed for high-pressure reactions with a fixed weight ratio of glycerin to acetic acid by considering the volume change arising from the generation of water during the reaction. The yield of DCP was found to be maximized at 130°C and 6 bar. The modified kinetic parameters and high-pressure reaction model were evaluated by high-accuracy fitting to experimental data. The results allowed the creation of a kinetic model suitable for application to DCP synthesis from glycerin and anhydrous HCl at high pressures.

• 社団法人 化学工学会の論文
• 2011-07-01

著者

• Bae Jong

  Department Of Chemical Engineering And School Of Environmental Engineering Pohang University Of Scie

• Lim Jong

  Department Of Advanced Materials Science And Engineering Sungkyunkwan University

• SONG Won

  Production Technology Center, Samsung Fine Chemicals Co. Ltd.

• KWON Myeong

  Production Technology Center, Samsung Fine Chemicals Co. Ltd.

• WOO Sung

  Production Technology Center, Samsung Fine Chemicals Co. Ltd.

• SUNG Su

  Department of Chemical Engineering, Kyungpook National University

• Bae Jong

  Department Of Chemical Engineering Sungkyunkwan University

• Song Won

  Production Technology Center Samsung Fine Chemicals Co. Ltd.

• Lim Jong

  Department Of Chemical Engineering Sungkyunkwan University

• Lee Dong

  Department Of Aerospace Engineering Chonbuk National University

• Woo Sung

  Production Technology Center Samsung Fine Chemicals Co. Ltd.

• Sung Su

  Department Of Chemical Engineering Kyungpook National University

• Kwon Myeong

  Production Technology Center Samsung Fine Chemicals Co. Ltd.

• Lim Jong

  Department of Advanced Materials Engineering, Sungkyunkwan University, Suwon, Gyunggi-do 440-746, Korea

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