The Synthesis of D-(6R)- and (6S)-(6-2H1)-Galactose
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概要
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D-(6R)- and (6S)-(6-2H1)-Galactose were regio- and stereospecifically synthesized through photobromination of 1, 6-anhydrogalactose derivatives. The (6S)-compound was prepared in a similar manner to our previous synthesis of D-(6S)-(6-2H1)-glucose. The inversion to the (6R)-galacto derivatives was performed via (6S)-(6-2H1)-6-ρ-toluenesulfonyl-l, 2;3, 4-di-O-isopropyridene-α-D-galactose.
- 社団法人 日本農芸化学会の論文
著者
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OHRUI Hiroshi
Department of Applied Biological Chemistry, Faculty of Agriculture, Tohoku University
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MEGURO Hiroshi
Department of Applied Biological Chemistry, Faculty of Agriculture, Tohoku University
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Ohrui Hiroshi
Department Of Applied Biological Chemistry Faculty Of Agriculture Tohoku University
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Meguro Hiroshi
Department Of Applied Biological Chemistry Faculty Of Agriculture Tohoku University
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NISHIDA Yoshihiro
Department of Molecular Design and Engineering, Graduate School of Engineering, Nagoya University, C
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Nishida Yoshihiro
Department Of Applied Biological Chemistry Faculty Of Agriculture Tohoku University
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Meguro Hiroshi
Department Of Agricultural Chemistry Faculty Of Agriculture University Of Tokyo
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MEGURO Hiroshi
Department of Food Chemistry, Faculty of Agriculture, Tohoku University
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OHRUI Hiroshi
Department of Food Chemistry, Faculty of Agriculture, Tohoku University
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