Synthesis of (6R)- and (6S)-D-Glucose-6-2H through Stereospecific Photo-bromination of 1, 6-Anhydro-β-D-glucopyranose Derivative

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概要

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• A photo-bromination of l, 6-anhydro-2, 3, 4-tri-O-benzoyl-β-D-glucopyranose and its [6, 6-2H2]-derivative gave the corresponding (6S) 6-bromocompounds stereospecifically. They were transformed into (6S)-D-glucose-6-2H and (6R)-D-glucose-6-2H respectively.

• 社団法人 日本農芸化学会の論文

著者

• Ohrui Hiroshi

  Department Of Applied Biological Chemistry Faculty Of Agriculture Tohoku University

• Meguro Hiroshi

  Department Of Agricultural Chemistry Faculty Of Agriculture University Of Tokyo

• KISHI Hisashi

  Department of Animal Reproduction, National Institute of Agrobiological Resource

• HORIKI Hiroyuki

  Department of Food Chemistry, Faculty of Agriculture, Tohoku University

• KISHI Hisashi

  Department of Food Chemistry, Faculty of Agriculture, Tohoku University

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