麦門冬成分の研究(第1報) : シャノヒゲ(Ophiopogon japonicus Ker-Gawler var. genuinus MAXIM.)塊茎よりステロイド配糖体の分離

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概要

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• Examinations were made on the chemical components of the rhizome of Ophiopogon japonicus KER-GAWLBR var. genuinus MAXIM. (Liliaceae). Four kinds of glycoside were isolated in crystaline form and were named ophiopogonin-A, -B, -C, and -D. Ophiopogonin-A formed colorless needles (from hydrated ethanol), mp 183°, [α]^<29.0>_D-98.8°(pyridine) ; ophiopogonin-B, colorless needles (from ethanol), mp 269-271°, [α]^<15.0>_D-105.5°(pyridine) ; ophiopogonin-D, colorless needles (from hydrated ethanol), mp 263-265°, [α]^<14.0>_D-107.9°(pyridine). Ophiopogonin-C formed colorless needles (from water-saturated ethyl acetate), mp 187° The genin portion of ophiopogonin-A, -B, and-D is ruscogenin in all. The sugar portion of ophiopogonin-B consists of fucose and rhamnose, and that of ophiopogonin-D, fucose, rhamnose, and xylose. Ophiopogonin-A was found to be the partially acetylated compound of ophiopogonin-B. In addition to these substances, the presence of β-sitosterol, stigmasterol, and β-sitosterol-β-D-glucoside in the ether-soluble portion was clarified.

• 公益社団法人日本薬学会の論文
• 1968-06-25

著者

• 庄司 順三

  昭和大学薬学部

• 佐久間 聖一

  School of Pharmaceutical Sciences, Showa University

• 川西 幸子

  School Of Pharmaceutical Sciences Showa University

• 多田 晶寛

  School Of Pharmaceutical Sciences Showa University

• 川西 幸子

  昭和大学薬学部

• 加藤 ひさ子

  昭和大学薬学部

• 佐久間 聖一

  昭和大学薬学部

• 多田 晶寛

  昭和大学薬学部

• 佐久間 聖一

  School Of Pharmaceutical Sciences Showa University

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