竹節人参の成分研究(第2報) : Chikusetsusaponin IVの構造およびAraloside Aとの関係について

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概要

• 論文の詳細を見る

• Examinations were made on the chemical structure of chikusetsusaponin (IV), C_<47>H_<74>-O_<18>・4H_2O, mp>235°(decomp.), [α]^<19>_D-9.7°(pyridine), a crystalline saponin isolated from the rhizome of Panax japonicum. The structure was established as represented by formula (1) which agrees with the structure of araloside-A proposed by Kochetkov and others, but their direct comparison could not be made. In the present series of work, the compound O (10) was determined by microbial decomposition. In addition, isolation of erythrodiol 2,3-di-O-methyl-β-D-glucopyranoside by partial decomposition of erythrodiol bioside (3) made it cleasr that L-arabinose makes an α-furanoside bonding with glucuronic acid.

• 社団法人日本薬学会の論文
• 1969-06-25

著者

• 庄司 順三

  昭和大学薬学部

• 近藤 紀子

  Department Of Pharmacognosy School Of Pharmaceutical Sciences Showa University

• 近藤 紀子

  昭和大学薬学部

• 南雲 昇

  昭和大学薬学部

• 小松 信彦

  昭和大学薬学部

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