Dibenzothiophenes and Related Compounds. VI. Reactions of Cyclic Sulfonium Salts with Sodium Alkoxides and Benzenethiolate in Alcohols

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概要

• 論文の詳細を見る

• The reactions of 5-substituted dibenzothiophenium salts, having one or two substituents, with sodium alkoxides and benzenethiolate have been studied in the protic solvents. The results in Table I showed that the 5-substituted dibenzothiophenium salts with alkoxide ions mostly proceed via aromatic bimolecular nucleophilic substitution and ligand exchange as shown in Chart 7. It has been also found that the reactions of 5-substituted dibenzothiophenium salts with benzenethiolate ion support the validity of the mechanism proceed by the aromatic bimolecular nucleophilic substitution as shown in Table II.

• 公益社団法人日本薬学会の論文
• 1974-09-25

著者

• 片岡 貞

  Gifu Pharmaceutical University

• 清水 洋

  Gifu Pharmaceutical University

• 堀 幹夫

  Gifu Pharmaceutical University

• 高木 隆

  Research Laboratories, Morishita Pharmaceutical Co. Ltd.

• 宮垣 充弘

  Gifu College Of Pharmacy

• 高木 隆

  Research Laboratories Morishita Pharmaceutical Co. Ltd.

• 高木 隆

  Gifu College of Pharmacy

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