Reaction of Conjugated Dienones with Hydrazoic Acid

スポンサーリンク

概要

• 論文の詳細を見る

• The reaction of conjugated dienones (V, XII, XV, and XVII) with hydrazoic acid was examined. From the substrates (V and XII), the keto-lactam derivatives (VI, VII, VIII, and IX) were formed by the action of two moles of hydrazoic acid. From the other substrate (XV), a lactam derivative, a normal Schmidt reaction product, was obtained. The cross-conjugated dienone (XVII) could not react with hydrazoic acid in PPA, but gave a dienone-phenol rearrangement product. A possible pathway to the formation of ketolactam derivatives (VI-IX) from V was presented.

• 公益社団法人日本薬学会の論文
• 1971-10-25

著者

• 野村 敬一

  Faculty Of Pharmaceutical Sciences Toyama Medical And Pharmaceutical University

• 三橋 監物

  Faculty Of Pharmaceutical Sciences Josai University

• 三由 文久

  Faculty Of Pharmaceutical Sciences University Of Toyama

関連論文

• Studies on Mesoionic Compounds. XII. Synthesis of 1,2,3-Thiadiazolium-4-aminide Derivatives and Their Characterization
• Studies on Mesoionic Compounds. XIV. Synthesis of Mesoionic 1,3-Thiazolium-4-thiolates
• Studies on Mesoionic Compounds. XIII. Synthesis of Mesoionic 1,2,3-Thiadiazolium-4-thiolates
• Studies on Mesoionic Compounds. IX. Synthesis of Bicyclic Mesoionic Compounds
• Studies on Mesoionic Compounds. VIII. Some Reactions of the Mesoionic 4-Amino-1,2,4-triazolium-3-thiolate System
• Studies on Mesoionic Compounds. V. Synthesis and Cycloaddition Reaction of anhydro-5-Hydroxy-1,3-oxathiolium Hydroxide System
• Introduction of a 3-Alkoxycarbonyl-2-propenyl Group at the ortho Position of Phenol and Naphthol via α-Aryloxy-γ-butyrolactone. Application to Syntheses of (±)-Nanaomycin A and a 1-Anthracenone
• Syntheses of 5,6-Benzo- and 5,6-Naphtho-(1R, 3R, 4S, 8R)-4,8-dihydroxy-3-methyl-2-oxabicyclo [2.2.2] oct-5-ene Derivatives
• Studies on Structure-Activity Relationship of Analgetics. XIII. Syntheses of Homobenzomorphans and Related Compounds. (1)
• SYNTHESIS OF THE B/C-RING SYSTEM OF TETRONASIN (ICI-139603)
• SYNTHESIS OF THE POLYETHER FRAGMENT A/B-RING SYSTEM OF TETRONOMYCIN
• SYNTHESES OF THE TETRAHYDROFURAN SUBUNITS OF TETRONASIN AND TETRONOMYCIN
• AN EFFICIENT 3(C)-ACYLATION OF TETRAMIC ACIDS INVOLVING ACYL MIGRATION OF 4(O)-ACYLATES(Communications to the Editor)
• AN EFFICIENT METHOD FOR 3(C)-ACYLATION OF TETRONIC ACIDS(Communications to the Editor)
• Cyanophthalide Annulation with 4-(5-Alkoxy-2-furyl)-3-buten-2-one. Application to the Synthesis of a (Naphtho)pyrano-γ-lactone
• Heteroaromatic Analogs of Benzomorphan. III. Synthesis of 1,2,3,4,5,6-Hexahydro-2,6-methano-3-methylpyrido [3,2-d] azocine
• Heteroaromatic Analogs of Benzomorphan. II. Synthesis of 2-Azabicyclo-[3.3.1] nonane Derivatives fused to Pyridine Ring. (2)
• Reaction of Conjugated Dienones with Hydrazoic Acid. II.
• Tetrahydronaphthylamines and Related Compounds. III. Synthesis of 1,2,3,4-Tetrahydro-2-naphthylamine and 6-Amino-5,6,7,8-tetrahydroquinoline Derivatives
• Synthesis of 1,2,3,4,5,6-Hexahydro-1,5-methano-2-methylpyrido [2,3-c] azocine
• エノールエーテルと窒化水素酸との反応
• Thiazole Analogs of Benzomorphans. II. Synthesis of Novel Thiazolo [5,4-f] morphans
• Thiazole Analogs of Benzomorphans. I. Synthesis of Novel Thiazolo [4,5-f] morphans
• Heteroaromatic Analogs of Benzomorphan. Synthesis of Novel Thiazolo [4,5-f] morphans
• 2-Ethylenedioxy-7-azabicyclo[4.1.0]heptaneの合成と加水分解反応
• Tetrahydronaphthylamines and Related Compounds. II. Synthesis of 1,2,3,4-Tetrahydro-6,7-dimethoxy-2-phenyl-2-naphthylamine
• Syntheses of 1,2,3,4-Tetrahydro-2-naphthylamine Derivatives
• Synthesis of Homobenzomorphans and the Related Compounds. III. 3-Methyl-2,3,4,5,6,7-hexahydro-1,6-methano-1H-3-benzazonine
• On the Cleavage of Tertiary Amines with Ethyl Chloroformate
• Mass Spectral Studies of Aza- and Diazabenzobicycloalkanes. II. Some Aspects of Mass Spectrometry of 1,3-Bridged 1,2,3,4-Tetrahydronaphthalenes, 2,4-Bridged 1,2,3,4-Tetrahydroisoquinolines and 1,3-Bridged 1,2,3,4-Tetrahydroquinolines
• Mass Spectral Studies of Aza-and Diazabenzobicycloalkanes. I. Some Aspects of Mass Spectrometry of 1,3-Bridged 1,2,3,4-Tetrahydroisoquinolines
• Studies on Structure-Activity Relationship of Analgetics. X. Syntheses of 11-Amino-2,3-benzobicyclo [3. 3. 1] nonane and 3-Phenyl-9-amino-bicyclo [3. 3. 1] nonane Derivatives.
• Syntheses of Azabenzobicycloalkanes
• Studies on Diazabenzobicyclo [3.3.1] nonane System. VIII. Synthesis of 8,9-Dimethoxy-11-benzoyl-1,2,5,6-tetrahydro-2,6-imino-3-benzazocin-4 (3H)-one
• Studies on Diazabenzobicyclo [3.3.1] nonane System. VII. Synthesis of 1,2,3,4,5,6-Hexahydro-1,5-methanobenzo [e][1,2] diazocine Derivatives and an Example of Abnormal Cleavage of Hydrazide by Lithium Aluminum Hydride
• Studies on Diazabenzobicyclo [3.3.1] nonane System. VI. Syntheses of 1,2,3,4-Tetrahydro-6H-1,5-methanobenzo [d][1,2] diazocine Derivatives
• Studies on Diazabenzobicyclo-[3.3.1]nonane System. V. Nuclear Magnetic Resonance Spectral Studies on Diazabenzobicyclo[3.3.1]nonane System
• Studies on Diazabenzobicyclo [3.3.1] nonane System. IV. Synthesis of 1,2,3,4,5,6-Hexahydro-1,5-methanobenzo [e] [1,3] diazocine Derivatives
• Studies on Diazabenzobicyclo [3.3.1] nonane System. I. Syntheses of 3,4,5,6-Tetrahydro-2H-1,5-methanobenzo [g]-[1,4] diazocine and its Derivatives.
• A New Synthesis of 6,7-Benzomorphan
• The Reaction of α, β-Unsaturated Ketones with Azides. III.
• Thiazole Analogs of Benzomorphans. III. Syntheses of 4,5,6,7,8,9-Hexahydro-4,8-methano-5-methylthiazolo [4,5-c] azocine and 4,5,6,7,8,9-Hexahydro-4,8-methano-5-methylthiazolo [5,4-c] azocine
• Reaction of Conjugated Dienones with Hydrazoic Acid
• The Reaction of α, β-Unsaturated Cycloalkenones with Azides. I. The Anomalous Products in the Schmidt Reaction

もっと見る 閉じる

スポンサーリンク