The Reaction of α, β-Unsaturated Cycloalkenones with Azides. I. The Anomalous Products in the Schmidt Reaction
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概要
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2-Methyl-(Ia), 2-phenyl-(Ib), 3-methyl-2-cyclohexenone (Xa) and 2-cyclohexenone (Xc) were reacted with equivalent mole of sodium azide in polyphosphoric acid. In all cases, 2-amino-2-cyclohexenone derivatives were yielded as abnormal reaction products. In the cases of Ia and Ib, migration of the methyl and the phenyl group to the position 3 was observed accompanied by the simultaneous introduction of an amino group at the position 2,respectively.
- 公益社団法人日本薬学会の論文
- 1965-08-25
著者
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野村 敬一
Faculty Of Pharmaceutical Sciences Toyama Medical And Pharmaceutical University
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三橋 監物
Faculty Of Pharmaceutical Sciences Josai University
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