Fungal Metabolites. XIII. Isolation and Structural Elucidation of New Peptaibols, Trichodecenins-I and -II, from Trichoderma viride

概要

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Three new groups of peptaibols, trichodecenins, trichorovins and trichocellins, have been isolated from conidia of the fungus, Trichoderma viride. The structures of trichodecenins-I and -II were established by positive-ion fastatom bombardment, collision-induced dissociation mass spectrometry and two-dimensional NMR spectroscopy. Trichodecenins-I and -II have a (Z)-4-decenoyl group, six amino acid residues and a leucinol moiety in the molecules. Trichodecenin-II was synthesized by the solution-phase method.
社団法人日本薬学会の論文
1994-03-15