Solute-Stationary Phase Interaction in Gas-Liquid Chromatography. : Evaluation of the Relative Retention Value for Substituted Halogenobenzene Derivatives
スポンサーリンク
概要
- 論文の詳細を見る
Separation coefficients log γ for substituted halgenobenzene derivatives given by gas-liquid chromatography have been evaluated by regression analysis, using three kinds of descriptors, namely, σ_<s°>, μ^2/α and Σσ^±_π. For the orthodisubstituted series, the descriptor Σσ^±_π, correcting the ortho effect due to the vicinal substituent group, is required. This correction can be achieved by evaluating the intensity drop of the p(^1La) band of ultraviolet absorption spectra. The Σσ^±_π of the regreession equation indicates the contribution of the charge-transfer interactionbetween the substrate and stationary liquid.
- 公益社団法人日本薬学会の論文
- 1990-04-25
著者
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川木 秀子
Faculty of Pharmaceutical Sciences, Kinki University
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佐々木 喜男
Faculty of Pharmaceutical Sciences, Osaka University
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佐々木 喜男
Faculty Of Pharmaceutical Sciences Osaka University
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高木 達也
Faculty of Pharmaceutical Sciences, Osaka University
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高木 達也
Genome Information Research Center Osaka University
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藤井 志保
Faculty of Pharmaceutical Sciences, Osaka University
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升田 史佳
Faculty of Pharmaceutical Sciences, Osaka University
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藤井 志保
Faculty Of Pharmaceutical Sciences Osaka University
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川木 秀子
Faculty Of Pharmaceutical Sciences Kinki University
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升田 史佳
Faculty Of Pharmaceutical Sciences Osaka University
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