Studies on the Proton Magnetic Resonance Spectra in Aromatic Systems. IX. Calculation of π-Electron Charge Density Distribution of the Substituted Benzene and Naphthalene Derivatives and ω-Technique
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概要
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ρNMR-π-electron charge density estimated from the revised shielding parameter-showed appreciable disagreement with that from HMO calculation using Streitwieser's parameter especially at meta position. The ω-technique has been applied to settle this problem and parameters for above treatment have been arranged so as to reconcile with ρNAR. Above treatments have also been applied to 1-substituted-3,4-dimethoxybenzene, 2-substituted- and 2-substituted-6-methoxynaphthalene series, and favorable results have been acknowledged.
- 公益社団法人日本薬学会の論文
- 1969-06-25
著者
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鈴木 美代子
Faculty Of Pharmaceutical Sciences Osaka University
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佐々木 喜男
Faculty Of Pharmaceutical Sciences Osaka University
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